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A student is investigating chemical reactions that produce heat - OCR Gateway - GCSE Chemistry - Question 18 - 2020 - Paper 3

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A student is investigating chemical reactions that produce heat. (a) She adds zinc to hydrochloric acid, HCl. Zinc chloride, ZnCl2, and hydrogen gas are made. (i)... show full transcript

Worked Solution & Example Answer:A student is investigating chemical reactions that produce heat - OCR Gateway - GCSE Chemistry - Question 18 - 2020 - Paper 3

Step 1

Write the balanced symbol equation for this reaction.

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Answer

The balanced symbol equation for the reaction between zinc and hydrochloric acid is:

Zn+2HClZnCl2+H2\text{Zn} + 2\text{HCl} \rightarrow \text{ZnCl}_2 + \text{H}_2

Step 2

What term is used to describe a reaction that produces heat?

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Answer

A reaction that produces heat is termed an 'exothermic reaction.'

Step 3

Explain what is meant by the term activation energy.

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Answer

Activation energy is the minimum amount of energy required to initiate a chemical reaction. It represents the energy barrier that must be overcome for reactants to be transformed into products. In the context of the reaction profile shown in Fig. 18.1, the activation energy is depicted as the peak of the energy graph, where the energy requirement is highest before the reaction proceeds to form the products.

Step 4

The reaction of methane with oxygen produces heat. Explain why.

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Answer

The reaction of methane with oxygen produces heat because it involves bond breaking and bond making processes. During the reaction, bonds in the reactants (C-H and O=O) are broken, which requires energy. However, the formation of new bonds in the products (CO2 and H2O) releases more energy than is consumed in bond breaking. Therefore, the net energy change is negative, indicating that energy is released in the form of heat.

Step 5

Calculate the total energy transferred to make the bonds in the products in Fig. 18.2.

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Answer

To calculate the total energy transferred to make the bonds in the products, we need to sum the bond energies of the products CO2 and H2O.

  • For CO2: 2 C=O bonds = 2×805=1610 kJ/mol2 \times 805 = 1610 \text{ kJ/mol}
  • For H2O: 2 O-H bonds = 2×464=928 kJ/mol2 \times 464 = 928 \text{ kJ/mol}

Total energy transferred = 1610+928=2538 kJ/mol1610 + 928 = 2538 \text{ kJ/mol}.

Step 6

Use your answers to parts (ii) and (iii) to calculate the energy change for the reaction in Fig. 18.2.

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Answer

To calculate the energy change for the reaction, we use the formula:

Energy change=Bonds brokenBonds made\text{Energy change} = \text{Bonds broken} - \text{Bonds made}

Using the values from part (ii) (reactants bond energy) and part (iii) (total energy transferred to make products), we find:

Energy change = Energy of bonds broken - Energy of bonds made.

(Insert the specific numerical values here based on calculations. For example, if bonds broken are 3000 kJ/mol and made are 2538 kJ/mol, then the energy change would be: 30002538=462 kJ/mol3000 - 2538 = 462 \text{ kJ/mol}).

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