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A chemist analysed a mixture of four dyes, A, B, C and D, using gas-liquid chromatography - Scottish Highers Chemistry - Question 16 - 2023

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Question 16

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A chemist analysed a mixture of four dyes, A, B, C and D, using gas-liquid chromatography. The time taken to travel through the column (retention time) depends on th... show full transcript

Worked Solution & Example Answer:A chemist analysed a mixture of four dyes, A, B, C and D, using gas-liquid chromatography - Scottish Highers Chemistry - Question 16 - 2023

Step 1

Which of the following compounds corresponds to peak Z?

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Answer

To determine which compound corresponds to peak Z, we need to analyze the retention times of the dyes A, B, C, and D based on their polarities.

Peak Z appears earlier than the other peaks, indicating it is the least polar among the compounds. Consequently, among the structures provided:

  • Dye A features multiple hydroxyl groups, suggesting higher polarity.
  • Dye B has fewer hydroxyl groups compared to Dye A and could be less polar.
  • Dye C also has multiple hydroxyls, increasing its polarity.
  • Dye D has the most hydroxyl groups, leading to the highest polarity.

Analyzing these structures, Dye B appears to have the right configuration to reflect low polarity, corresponding with peak Z on the chromatogram.

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