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Plants require trace metal nutrients, such as zinc, for healthy growth - Scottish Highers Chemistry - Question 10 - 2015

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Plants require trace metal nutrients, such as zinc, for healthy growth. Zinc ions are absorbed from soil through the plant roots. The zinc ion concentration in a so... show full transcript

Worked Solution & Example Answer:Plants require trace metal nutrients, such as zinc, for healthy growth - Scottish Highers Chemistry - Question 10 - 2015

Step 1

(i) Explain fully why the flask was left for 24 hours, without a stopper.

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Answer

The flask was left for 24 hours to allow sufficient time for the zinc to fully react with sulfuric acid. During this reaction, hydrogen gas is produced as a byproduct. Without a stopper, the hydrogen gas escapes from the flask, preventing pressure buildup and ensuring the reaction can proceed smoothly.

Step 2

(ii) Explain why the student should use deionised water or distilled water, rather than tap water, when preparing the stock solution.

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Answer

The student should use deionised or distilled water instead of tap water because tap water may contain zinc ions, impurities, or other metal ions that could interfere with the accuracy of the zinc ion concentration in the solution.

Step 3

(b) (i) Name the piece of apparatus which should be used to transfer 10 cm³ of stock solution to a standard flask.

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Answer

The appropriate apparatus for transferring 10 cm³ of stock solution is a pipette.

Step 4

(ii) Calculate the concentration, in mg l⁻¹, of the solution prepared by transferring 10 cm³ of the 1 g l⁻¹ stock solution to a 1000 cm³ standard flask and making up to the mark.

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Answer

To calculate the concentration of zinc ions in the diluted solution, use the formula:

C1V1=C2V2C_1V_1 = C_2V_2

Where:

  • C1C_1 = initial concentration = 1 g l⁻¹ = 1000 mg l⁻¹
  • V1V_1 = volume of stock solution transferred = 10 cm³ = 0.01 l
  • C2C_2 = final concentration (unknown)
  • V2V_2 = final volume after dilution = 1000 cm³ = 1 l

Plugging in the values:

1000extmgl1imes0.01extl=C2imes1extl1000 ext{ mg l}^{-1} imes 0.01 ext{ l} = C_2 imes 1 ext{ l}

Calculating:

C_2 = rac{10 ext{ mg}}{1 ext{ l}} = 10 ext{ mg l}^{-1}

Step 5

(c) Determine the concentration, in mg l⁻¹, of zinc ions in the solution.

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Answer

To determine the concentration based on an absorbance of 0.3, refer to the calibration curve of absorbance vs. concentration (as plotted). By applying the best-fit line or using interpolation based on the given data, the concentration of zinc ions corresponding to an absorbance of 0.3 falls within the range of 4.6 to 4.8 mg l⁻¹.

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