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Modern shellac nail varnishes are more durable and so last longer than traditional nail polish - Scottish Highers Chemistry - Question 7 - 2016

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Modern shellac nail varnishes are more durable and so last longer than traditional nail polish. (a) The Skin Care Foundation has recommended that a sun-block is app... show full transcript

Worked Solution & Example Answer:Modern shellac nail varnishes are more durable and so last longer than traditional nail polish - Scottish Highers Chemistry - Question 7 - 2016

Step 1

Suggest why the Skin Care Foundation makes this recommendation.

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Answer

The Skin Care Foundation recommends the use of sun-block because UV light can be harmful to the skin. It can cause sunburn, initiate free radical formation, lead to premature aging, and increase the risk of skin cancer.

Step 2

State what is meant by the term free radical.

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Answer

A free radical is a species that has one or more unpaired electrons, making it highly reactive.

Step 3

State the term used to describe this type of step in a free radical chain reaction.

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Answer

This step is referred to as initiation.

Step 4

Name the functional group circled above.

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Answer

The functional group is a carboxylic acid.

Step 5

State why propan-2-ol can be described as a secondary alcohol.

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Answer

Propan-2-ol is classified as a secondary alcohol because the hydroxyl group (-OH) is attached to a carbon atom that is bonded to two other carbon atoms.

Step 6

Draw a structural formula for butyl ethanoate.

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Answer

The structural formula for butyl ethanoate is:

       H   H   H
       |   |   |
  H - C - C - O - C - C - H
       |   |   |
       H   H   H

Step 7

Suggest why a wet paper towel is wrapped around the test tube.

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Answer

A wet paper towel is wrapped around the test tube to condense any vapors or reactants, which helps in the cooling process and prevents the loss of reactants.

Step 8

Calculate the percentage yield of ethyl ethanoate.

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Answer

To calculate the percentage yield, we first need to determine the theoretical amount of ethyl ethanoate produced from 2.5 g of ethanol. The molar mass of ethanol is 46 g/mol.

  1. Calculate moles of ethanol:

    2.5extg/46extg/mol=0.054extmoles2.5 ext{ g} / 46 ext{ g/mol} = 0.054 ext{ moles}

  2. Theoretical yield of ethyl ethanoate from this reaction is equivalent to this amount since the reaction produces 1 mole of ethyl ethanoate per mole of ethanol.

  3. Now, the mass of the ethyl ethanoate produced can be calculated:

    Theoretical mass = moles × molar mass = 0.054extmoles×88extg/mol=4.752extg0.054 ext{ moles} × 88 ext{ g/mol} = 4.752 ext{ g}

  4. The actual yield obtained is 2.9 g.

  5. Percentage yield = rac{ ext{actual yield}}{ ext{theoretical yield}} × 100 = rac{2.9 ext{ g}}{4.752 ext{ g}} × 100 ≈ 60.9 ext{ %}.

Step 9

Name the type of reaction that takes place during the formation of ethyl ethanoate.

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Answer

The type of reaction that takes place is called condensation.

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