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Dishwasher tablets contain chemicals which remove dirt from dishes - Scottish Highers Chemistry - Question 9 - 2017

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Dishwasher tablets contain chemicals which remove dirt from dishes. (a) Dishwasher tablets include detergents. These molecules act like soaps to allow mixing of fat... show full transcript

Worked Solution & Example Answer:Dishwasher tablets contain chemicals which remove dirt from dishes - Scottish Highers Chemistry - Question 9 - 2017

Step 1

(a)(i) Complete the diagram below to show how detergent molecules combine with fat-soluble dirt.

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Answer

To complete the diagram, draw at least one detergent molecule with its hydrophilic (water-attracting) head nearing the water phase and the hydrophobic (fat-attracting) tail embedded in the fat-soluble dirt. This shows the interaction between the detergent molecules and the fat-soluble dirt.

Step 2

(b)(i) Suggest another action of the bleach produced by the dishwasher tablets.

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Answer

Another action of the bleach produced by the dishwasher tablets is to break down colored compounds or to disinfect surfaces, effectively removing stains or killing bacteria.

Step 3

(b)(ii) Calculate the volume of oxygen gas that would be produced when 0.051 g of hydrogen peroxide decomposes.

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Answer

First, calculate the moles of hydrogen peroxide:

Moles of H2O2=0.051 g34 g/mol=0.0015 mol\text{Moles of } H_2O_2 = \frac{0.051 \text{ g}}{34 \text{ g/mol}} = 0.0015 \text{ mol}

Using the reaction, 2 moles of H2O2 produce 1 mole of O2:

Moles of O2=0.0015 mol H2O2×1extmolO22extmolH2O2=0.00075extmol\text{Moles of } O_2 = 0.0015 \text{ mol } H_2O_2 \times \frac{1 ext{ mol } O_2}{2 ext{ mol } H_2O_2} = 0.00075 ext{ mol}

To find the volume of oxygen gas:

Volume=0.00075 mol×24 L/mol=0.018 L\text{Volume} = 0.00075 \text{ mol} \times 24 \text{ L/mol} = 0.018 \text{ L}

Step 4

(c)(i) Name the small, water-soluble molecules made when proteins are broken down completely.

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Answer

The small, water-soluble molecules made when proteins are broken down completely are called amino acids.

Step 5

(c)(ii)(A) Name the functional group circled.

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Answer

The functional group circled is an amine group.

Step 6

(c)(ii)(B) Draw a structural formula for one of the molecules that would be made when this section of egg white protein chain is completely broken down.

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Answer

One of the molecules made when the section of egg white protein chain is completely broken down is glycine, which can be represented as:

  H   O
   \  ||
    N--C--H
   /  
  H   

Step 7

(c)(iii)(A) State the term used to describe the change in shape of enzyme molecules.

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Answer

The term used to describe the change in shape of enzyme molecules is denaturation.

Step 8

(c)(iii)(B) Suggest a change in conditions which would cause the enzyme molecules to change shape.

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A change in conditions that could cause the enzyme molecules to change shape is an increase in temperature or a change in pH.

Step 9

(d)(i) Suggest a name for this type of reaction.

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Answer

The type of reaction shown in the first stage of producing TAED is known as a condensation reaction.

Step 10

(d)(ii) Draw a structural formula for TAED.

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Answer

The structural formula for TAED can be represented as:

      O
      ||
H3C-N-CH2-CH2-N-CH2-CO-CH3
      |       | 
      H    H  

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