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Ethane-1,2-diol can be made from ethene - Scottish Highers Chemistry - Question 9 - 2018

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Ethane-1,2-diol can be made from ethene. (a) The flow chart of an industrial process to produce ethane-1,2-diol is shown. (i) Industrial processes are designed to m... show full transcript

Worked Solution & Example Answer:Ethane-1,2-diol can be made from ethene - Scottish Highers Chemistry - Question 9 - 2018

Step 1

Using the flowchart, suggest two ways to maximise profit in this industrial process.

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Answer

  1. Recycle (waste) gases back into the process to improve yield.
  2. Use a catalyst to increase the reaction rate, thereby reducing time and energy costs.

Step 2

Name the process used in Separator 2 to separate ethane-1,2-diol from the larger liquid by-products.

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Answer

The process is fractional distillation.

Step 3

Explain fully why ethane-1,2-diol is more viscous than propan-1-ol.

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Answer

Ethane-1,2-diol has a greater number of hydroxyl (-OH) groups compared to propan-1-ol, leading to more extensive hydrogen bonding between molecules. This increased intermolecular attraction requires more energy to overcome, resulting in higher viscosity.

Step 4

Draw a structural formula for a diol that contains three carbon atoms.

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Answer

Here is one possible structural formula for a three-carbon diol:

   HO-CH₂-CH-CH₂-OH

or simplified as:

   CH₂(OH)-CHOH-CH₂OH

Step 5

Describe the procedure that should be used to prepare 100 cm³ of the 20% ethanol solution.

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Answer

  1. Measure 20 cm³ of ethanol using a pipette.
  2. Transfer the measured ethanol into a 100 cm³ volumetric flask.
  3. Add distilled water to the flask gradually until the total volume reaches exactly 100 cm³.

Step 6

Calculate the total volume, in cm³, of the 20% ethanol solution needed to treat a 3-5 kg animal.

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Answer

For a 3-5 kg animal:

  1. Calculate the total ethanol solution needed per dose:
    Volume per dose = 5 cm³/kg × mass of animal (kg)
    If mass = 5 kg, then: Volume per dose = 5 cm³/kg × 5 kg = 25 cm³
  2. Total doses required = 9 doses.
  3. Total volume needed = 9 doses × 25 cm³ = 225 cm³.

Step 7

Draw a structural formula for another possible product of oxidation of ethane-1,2-diol.

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Answer

One possible product is glycolic acid, represented as:

   HO-CH(OH)-COOH

Step 8

Give a formula for sodium glycolate.

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Answer

The formula for sodium glycolate is NaC₂H₃O₃.

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