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Essential oils from the lavender plant are used in aromatherapy - Scottish Highers Chemistry - Question 10 - 2017

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Essential oils from the lavender plant are used in aromatherapy. (a) Gas chromatography can be used to separate and identify the organic compounds in lavender oils.... show full transcript

Worked Solution & Example Answer:Essential oils from the lavender plant are used in aromatherapy - Scottish Highers Chemistry - Question 10 - 2017

Step 1

(i) Calculate the relative concentration of linalool in lavender oil A.

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Answer

To find the relative concentration of linalool in lavender oil A, use the formula:

Relative concentration=(Component peak areaTotal peak area)×100%\text{Relative concentration} = \left( \frac{\text{Component peak area}}{\text{Total peak area}} \right) \times 100 \%

Here, the component peak area for linalool is 31909 and the total peak area is 79310. Substituting these values:

Relative concentration=(3190979310)×100%40.23%\text{Relative concentration} = \left( \frac{31909}{79310} \right) \times 100 \% \approx 40.23 \%

Step 2

(ii) Identify the component found in lavender oil A that is missing from lavender oil B.

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Answer

The component found in lavender oil A that is missing from lavender oil B is geranyl acetate (peak 5).

Step 3

(b) Calculate the cost, in pence, of 1,8-cineole that is present in a 500 cm³ bottle of this brand of mouthwash.

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Answer

First, determine the total amount of 1,8-cineole in a 500 cm³ bottle:

Amount=0.92 mg/cm3×500 cm3=460 mg\text{Amount} = 0.92 \text{ mg/cm}^3 \times 500 \text{ cm}^3 = 460 \text{ mg}

Next, convert the mass from mg to kg:

460 mg=0.460 g=0.000460 kg460 \text{ mg} = 0.460 \text{ g} = 0.000460 \text{ kg}

Using the cost of £59.10 per kg, calculate the cost:

Cost=0.000460 kg×£59.10/kg£0.027166\text{Cost} = 0.000460 \text{ kg} \times £59.10/\text{kg} \approx £0.027166

To convert this cost to pence (1 pound = 100 pence):

0.027166×100=2.7166 pence0.027166 \times 100 = 2.7166 \text{ pence}

Rounded to a suitable amount, the cost is approximately 2.72 pence.

Step 4

(c i) Circle the chiral carbon atom in the linalool structure.

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Answer

In the structure of linalool shown, the chiral carbon atom is the one attached to the hydroxyl (OH) group and is bound to four different groups: H, CH₃, CH₂, and OH. Therefore, it should be circled.

Step 5

(c ii) Write the molecular formula of farnesene.

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Answer

The molecular formula of farnesene is C₁₅H₂₄.

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