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Modern shellac nail varnishes are more durable and so last longer than traditional nail polish - Scottish Highers Chemistry - Question 7 - 2016

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Modern shellac nail varnishes are more durable and so last longer than traditional nail polish. (a) The Skin Care Foundation has recommended that a sun-block is app... show full transcript

Worked Solution & Example Answer:Modern shellac nail varnishes are more durable and so last longer than traditional nail polish - Scottish Highers Chemistry - Question 7 - 2016

Step 1

Suggest why the Skin Care Foundation makes this recommendation.

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Answer

The Skin Care Foundation recommends applying sun-block to protect the skin from harmful UV radiation, which can cause sunburn, accelerate skin aging, and increase the risk of skin cancer.

Step 2

State what is meant by the term free radical.

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Answer

A free radical is a species, such as an atom or molecule, that contains unpaired electrons and is highly reactive.

Step 3

State the term used to describe this type of step in a free radical chain reaction.

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Answer

This type of step is known as initiation.

Step 4

Name the functional group circled above.

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Answer

The functional group is a carboxylic acid.

Step 5

State why propan-2-ol can be described as a secondary alcohol.

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Answer

Propan-2-ol is a secondary alcohol because the hydroxyl group (-OH) is attached to a carbon that is bonded to two other carbon atoms.

Step 6

Draw a structural formula for butyl ethanoate.

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Answer

The structural formula for butyl ethanoate is:

  H   H   H   H
  |   |   |   |
H-C-C-C-C=O
  |   |   |   |
  H   O   H   H
      |   \
      H    O

Step 7

Suggest why a wet paper towel is wrapped around the test tube.

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Answer

A wet paper towel is wrapped around the test tube to condense any vapors or reactants that might evaporate during the reaction, ensuring that they return to the liquid state.

Step 8

Calculate the percentage yield of ethyl ethanoate.

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Answer

To calculate the percentage yield, first determine the theoretical yield. The molar mass of ethanol is 46 g/mol, and ethanoic acid is 60 g/mol.

  1. Calculate moles of ethanol:


    moles = mass/molar mass = 2.5 g / 46 g/mol ≈ 0.0543 mol

  2. According to the reaction stoichiometry, it produces an equal amount of ethyl ethanoate. Thus, the theoretical mass of ethyl ethanoate produced:


    theoretical mass = 0.0543 mol * 88 g/mol = 4.78 g.

  3. Actual yield = 2.9 g.

  4. Percentage yield = (actual yield / theoretical yield) * 100 = (2.9 g / 4.78 g) * 100 ≈ 60.7%.

Step 9

Name the type of reaction that takes place during the formation of ethyl ethanoate.

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Answer

The type of reaction that takes place is condensation.

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