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Which of the following ions could be used to oxidise iodide ions to iodine? $2I^-(aq) \rightarrow I_2(g) + 2e^-$ A - Scottish Highers Chemistry - Question 19 - 2016

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Which-of-the-following-ions-could-be-used-to-oxidise-iodide-ions-to-iodine?--$2I^-(aq)-\rightarrow-I_2(g)-+-2e^-$--A-Scottish Highers Chemistry-Question 19-2016.png

Which of the following ions could be used to oxidise iodide ions to iodine? $2I^-(aq) \rightarrow I_2(g) + 2e^-$ A. $SO_2^{2-}(aq)$ B. $SO_3^{2-}(aq)$ C. $Cr^{... show full transcript

Worked Solution & Example Answer:Which of the following ions could be used to oxidise iodide ions to iodine? $2I^-(aq) \rightarrow I_2(g) + 2e^-$ A - Scottish Highers Chemistry - Question 19 - 2016

Step 1

Identify the Oxidizing Agent

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Answer

To determine which ion can oxidise iodide ions (II^-) to iodine (I2I_2), we need to evaluate the potential oxidizing agents among the options available. An oxidizing agent is a substance that gains electrons in a reaction and, in doing so, causes the oxidation of another species.

Step 2

Evaluate Each Option

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Answer

  1. SO22(aq)SO_2^{2-}(aq): Sulfite ions can act as reducing agents, which makes them unlikely to oxidise iodide.

  2. SO32(aq)SO_3^{2-}(aq): Similar to sulfite, they can also behave as reducing agents and may not serve as oxidisers in this context.

  3. Cr3+(aq)Cr^{3+}(aq): Chromium ion in the +3 oxidation state is also more likely to act as a reducing agent, thus not suitable for oxidizing iodide.

  4. Cr2O72(aq)Cr_2O_7^{2-}(aq): The dichromate ion can act as a strong oxidizing agent, making it capable of oxidising iodide ions to iodine.

Step 3

Conclusion

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Answer

Based on the evaluations, the correct answer is D. Cr2O72(aq)Cr_2O_7^{2-}(aq).

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