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Required Practical: Investigating the Effect of Concentration on Rate of Reaction Simplified Revision Notes

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6.1.6 Required Practical: Investigating the Effect of Concentration on Rate of Reaction

Objective:

infoNote

To investigate how changing the concentration of hydrochloric acid influences the rate of a chemical reaction.

Overview:

  • Several experiments can determine the effect of varying concentrations on the rate of reaction. This practical involves two methods:
    1. Gas Collection Method: Measuring the volume of gas produced when magnesium reacts with hydrochloric acid.
    2. Disappearing Cross Method: Timing how long it takes for a reaction mixture to turn cloudy, obscuring a marked cross.

infoNote

Method 1 – Gas Collection:

  1. Prepare the Reactants: Clean a strip of magnesium using emery paper.
  2. Set Up the Reaction: Place the magnesium strip in a conical flask containing 25 cmÂł of a dilute hydrochloric acid solution.
  3. Collect the Gas: Quickly seal the flask with a bung connected to a delivery tube and a gas syringe. Start timing as soon as the acid is added.
  4. Measure Gas Volume: Record the volume of gas in the syringe every 10 seconds until the volume stops increasing.
  5. Final Measurement: Note the time when the gas volume stabilises.
  6. Repeat with Different Concentrations: Repeat the experiment with increasing concentrations of hydrochloric acid, increasing by equal increments, until reaching the highest concentration.

Method 2 – Disappearing Cross (Opaque Reaction Mixers):

  1. Set Up: Place a white tile with a black cross underneath a clear beaker.
  2. Prepare the Reaction Mixture: Add 25 cmÂł of sodium thiosulfate solution to the beaker.
  3. Start the Reaction: Add 25 cmÂł of hydrochloric acid to the beaker and start the timer immediately.
  4. Monitor the Cross: Observe the cross from above. Stop the timer when the cross is no longer visible through the cloudy reaction mixture.
  5. Record the Time: Note the time taken for the cross to disappear.
  6. Repeat with Different Concentrations: Repeat the experiment, increasing the concentration of hydrochloric acid incrementally, until reaching the highest concentration.

infoNote

Analysis:

  • Calculate the Reaction Rate: Use the collected data to determine the rate of reaction for each concentration.

  • Graph the Results: Plot the rate of reaction against the concentration of hydrochloric acid and draw a line of best fit.

  • Interpret the Graph: A steeper gradient suggests a higher rate of reaction as the concentration of hydrochloric acid increases.

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