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Kinetic Theory Simplified Revision Notes

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3.3.1 Kinetic Theory

Gases and Pressure

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The pressure, temperature, volume, and kinetic energy of a gas and its particles are interconnected. The particle model helps to explain these relationships and how altering one variable can impact the others.

Temperature and Pressure

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Temperature and pressure in a gas are directly related. The particles in a gas are constantly moving in random directions with varying speeds. When the temperature of the gas is increased, the following occurs:

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The increase in temperature results in a transfer of energy from heat to kinetic energy in the particles.

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Kinetic energy and speed are related by the equation:

K=1/2mv2K=1/2mv^2

So, as kinetic energy increases, the speed of the particles also increases.

  • Therefore, the average speed of the particles rises with temperature.
  • With increased speed, gas particles collide more frequently, both with each other and with the walls of the container they are in.
  • The pressure exerted by the gas is the total force applied by all the individual particles on the area of the container, which can be expressed as:
p=AFp=AF
  • Hence, an increase in temperature leads to an increase in the kinetic energy and speed of the particles, which in turn increases the pressure of the gas.
  • This relationship holds true only if the volume of the gas remains constant.

Pressure and Volume

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When the temperature of a gas remains constant, pressure and volume are inversely proportional. This means that as one increases, the other decreases. For example, if the volume of a gas is increased, its pressure will decrease because the gas particles are more spread out, leading to fewer collisions with the container walls.

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This inverse relationship can be expressed by the equation:

pV=constantpV=constant

Where:

  • pp is the pressure in pascals (Pa).
  • VV is the volume in cubic metres(m3). (m^3).
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For instance, if the volume of a gas (with constant temperature) is doubled, its pressure must halve to maintain the constant relationship between pressure and volume.

Increasing the Pressure of a Gas

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When energy is transferred by a force, this process is known as work. Doing work on a gas increases its internal energy, which, in turn, increases its temperature.

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An example of this is using a bike pump. When you push down on the lever, the gas inside the pump exerts a force on the lever. By applying force to push the lever down, you do work against this force, increasing the internal energy of the gas. As a result, the temperature of the gas—and the tyre—rises as you pump more air into it.

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