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Asparagusic Acid vs Allyl isothiocyanate Simplified Revision Notes

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Asparagusic Acid vs Allyl isothiocyanate

Chemistry

Asparagusic Acid vs Allyl isothiocyanate

Asparagusic Acid:

  • Contains a carboxyl group (COOH) with an O-H bond.
  • This functional group allows it to form hydrogen bonds with water molecules.

Allyl Isothiocyanate:

  • Contains non-polar bonds.
  • As a result, it cannot form hydrogen bonds with water molecules.

Cooking Methods:

Asparagus (Containing Asparagusic Acid):

  • Since asparagusic acid can form hydrogen bonds with water, it is better suited for cooking in water.
  • When asparagus is cooked in water, the polar asparagusic acid molecules dissolve in the water and are lost when the water is drained away.

Broccoli (Containing Allyl Isothiocyanate):

  • Allyl isothiocyanate, being non-polar, does not interact well with water.
  • Therefore, broccoli, which contains allyl isothiocyanate, should be cooked in a nonpolar cooking medium like oil.
  • When broccoli is cooked in oil, the non-polar allyl isothiocyanate molecules dissolve in the oil and are lost from the broccoli.

Considerations:

  • The choice of cooking method for these vegetables ensures that the flavour compounds are retained within the food.
  • However, there may be some trade-offs. For example, cooking asparagus in water may cause the loss of polar molecules like Vitamin C, which dissolve in water.

Summary:

  • Asparagusic acid (found in asparagus) is better preserved when cooked in water due to its ability to form hydrogen bonds with water molecules.
  • Allyl isothiocyanate (found in broccoli) is better retained when cooked in oil because it cannot form hydrogen bonds with water molecules.
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