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Use of the Data Booklet is relevant to this question - CIE - A-Level Chemistry - Question 15 - 2015 - Paper 1

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Use of the Data Booklet is relevant to this question. Which row correctly compares the electrical conductivity and first ionisation energy of magnesium and aluminiu... show full transcript

Worked Solution & Example Answer:Use of the Data Booklet is relevant to this question - CIE - A-Level Chemistry - Question 15 - 2015 - Paper 1

Step 1

Which row correctly compares the electrical conductivity and first ionisation energy of magnesium and aluminium?

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Answer

To answer this question, it is essential to understand the properties of magnesium and aluminium.

  1. Electrical Conductivity:

    • Aluminium is known for its high electrical conductivity, primarily due to its atomic structure which allows for free movement of electrons.
    • Magnesium, while a conductor, has lower conductivity compared to aluminium due to its lower number of free electrons.
    • Therefore, aluminium has higher electrical conductivity than magnesium.
  2. First Ionisation Energy:

    • First ionisation energy is the energy required to remove the outermost electron from an atom.
    • Generally, ionisation energy decreases down a group in the periodic table and increases across a period. Since magnesium is located below aluminium in the periodic table, it has a lower ionisation energy than aluminium.
    • Hence, aluminium has a higher first ionisation energy than magnesium.

With these points in mind, the correct answer is B: aluminium (higher electrical conductivity), magnesium (higher first ionisation energy).

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