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4(a) Copper carbonate reacts with dilute nitric acid - Edexcel - GCSE Chemistry: Combined Science - Question 4 - 2021 - Paper 1

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4(a) Copper carbonate reacts with dilute nitric acid. (i) During the reaction the copper carbonate powder completely disappears. State what can be deduced about the... show full transcript

Worked Solution & Example Answer:4(a) Copper carbonate reacts with dilute nitric acid - Edexcel - GCSE Chemistry: Combined Science - Question 4 - 2021 - Paper 1

Step 1

During the reaction the copper carbonate powder completely disappears.

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Answer

The fact that the copper carbonate powder completely disappears indicates that the acid used is in excess. This means that there was more acid available than was necessary to react with the copper carbonate.

Step 2

By what factor has the concentration of the hydrogen ions in the mixture changed?

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Answer

The pH change from 2 to 6 signifies an increase in alkalinity. The relationship between pH and hydrogen ion concentration is given by:

[H+]=10pH[H^+] = 10^{-pH}

Calculating the concentrations:

  • At pH 2: [H+]=102=0.01extM[H^+] = 10^{-2} = 0.01 ext{ M}
  • At pH 6: [H+]=106=0.000001extM[H^+] = 10^{-6} = 0.000001 ext{ M}

The factor of change in concentration is:

rac{0.01}{0.000001} = 10000

Thus, the answer is D × 1/10000.

Step 3

Describe what should be done to obtain copper sulfate crystals from this copper sulfate solution.

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Answer

To obtain copper sulfate crystals from the copper sulfate solution, follow these steps:

  1. Evaporate the Water: Gently heat the copper sulfate solution to evaporate some of the water, concentrating the solution. Be careful not to overheat as it may decompose the copper sulfate.

  2. Cool the Solution: Allow the concentrated solution to cool down slowly. As it cools, copper sulfate crystals will begin to form.

  3. Collect the Crystals: Once sufficient crystals have formed, filter the solution to separate the crystals from the remaining liquid.

  4. Dry the Crystals: Rinse the crystals with a small amount of cold distilled water to remove impurities, then allow them to dry in a warm place.

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