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8 (a) FA 5, FA 6 and FA 7 are solutions, some of which contain ions that are listed on pages 10 and 11 - CIE - A-Level Chemistry - Question 3 - 2017 - Paper 1

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8 (a) FA 5, FA 6 and FA 7 are solutions, some of which contain ions that are listed on pages 10 and 11. (i) To a 0.5 cm depth of solution in a boiling tube add aque... show full transcript

Worked Solution & Example Answer:8 (a) FA 5, FA 6 and FA 7 are solutions, some of which contain ions that are listed on pages 10 and 11 - CIE - A-Level Chemistry - Question 3 - 2017 - Paper 1

Step 1

(i) Identify as many ions present in FA 5, FA 6 and FA 7 as possible from your observations.

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Answer

Based on the observations:

  • FA 5: Cation present is likely extCu2+ ext{Cu}^{2+} (due to the formation of a blue precipitate with sodium hydroxide). Anion present could be ext{OH}^- (formation of precipitate).

  • FA 6: Cation is likely extFe2+ ext{Fe}^{2+} (indicated by the decolorization of the purple potassium manganate(VII) solution). Anion is unknown.

  • FA 7: Cation is extNa+ ext{Na}^+ (sodium in sodium nitrate), and anion is extNO3 ext{NO}_3^- (nitrate).

Step 2

(ii) Describe another test you could carry out to confirm the identity of a cation you have identified in (i).

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Answer

To confirm the presence of extFe2+ ext{Fe}^{2+} ions in FA 6, you can carry out a test using ammonium thiocyanate (NH₄SCN). When mixed with extFe2+ ext{Fe}^{2+} ions, it will produce a blood-red colored complex if extFe2+ ext{Fe}^{2+} is present. The expected observation would be a color change to blood red upon addition of the reagent.

  • Reagent: Ammonium thiocyanate (NH₄SCN).
  • Expected Observation: Formation of a blood-red colored solution.

Step 3

(iii) Write an ionic equation for the reaction that would occur in (ii).

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Answer

The ionic equation for the reaction that occurs between iron (II) ions and thiocyanate ions can be written as:

extFe2+(aq)+extSCN(aq)extFe(SCN)2+(aq) ext{Fe}^{2+}(aq) + ext{SCN}^{-}(aq) \rightarrow ext{Fe(SCN)}^{2+}(aq)

This indicates the formation of the complex ion, which gives the characteristic color.

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