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There are seven structural isomers with the molecular formula C5H10O that are carbonyl compounds - CIE - A-Level Chemistry - Question 4 - 2015 - Paper 1

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There are seven structural isomers with the molecular formula C5H10O that are carbonyl compounds. Four of these are aldehydes. These four aldehydes, A, B, C and D, ... show full transcript

Worked Solution & Example Answer:There are seven structural isomers with the molecular formula C5H10O that are carbonyl compounds - CIE - A-Level Chemistry - Question 4 - 2015 - Paper 1

Step 1

Give the structure of each of the four isomers.

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Answer

  1. Aldehyde A: The structure is linear, represented as:

    Structure of A:

    CH3-CH2-CH2-CHO

  2. Aldehyde B: The structure includes a chiral centre:

    Structure of B:

    CH3-CH(CH3)-CHO

  3. Aldehyde C: Contains two methyl groups:

    Structure of C:

    (CH3)2CH-CHO

  4. Aldehyde D: Contains three methyl groups:

    Structure of D:

    (CH3)3C-CHO

Step 2

Draw the three-dimensional structures of the two optical isomers of B.

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Answer

  1. Optical Isomer 1:

    Optical Isomer 1

  2. Optical Isomer 2:

    Optical Isomer 2

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