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An atom of potassium has atomic number 19 and mass number 39 - Edexcel - GCSE Chemistry: Combined Science - Question 5 - 2020 - Paper 1

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An atom of potassium has atomic number 19 and mass number 39. (i) Give the electronic configuration of this potassium atom. (ii) This potassium atom forms the ion ... show full transcript

Worked Solution & Example Answer:An atom of potassium has atomic number 19 and mass number 39 - Edexcel - GCSE Chemistry: Combined Science - Question 5 - 2020 - Paper 1

Step 1

Give the electronic configuration of this potassium atom.

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Answer

The electronic configuration of potassium (atomic number 19) can be expressed as:

2.8.8.12.8.8.1

This indicates that potassium has 2 electrons in the first shell, 8 in the second, 8 in the third, and 1 in the fourth shell.

Step 2

Which row shows the number of protons and the number of neutrons in this potassium ion, K⁺?

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For the potassium ion K⁺, the number of protons remains 19 (since protons define the element), and the mass number is 39. Thus, the number of neutrons can be calculated as:

Neutrons=Mass numberProtons=3919=20\text{Neutrons} = \text{Mass number} - \text{Protons} = 39 - 19 = 20

Therefore, the correct choice is B: 19 protons and 20 neutrons.

Step 3

Explain, in terms of electrons, why potassium and caesium are in the same group.

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Potassium (K) and caesium (Cs) belong to the same group in the periodic table because they both have the same number of electrons in their outermost shell. Specifically, both elements have one electron in their outer shell. This similarity in the arrangement of outer electrons leads to comparable chemical properties, such as their tendency to lose one electron and form +1 ions.

Step 4

Explain, in terms of these forces, why the boiling point of fluorine is low.

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Fluorine boils at -188°C due to the presence of weak intermolecular forces called van der Waals forces (or London dispersion forces). These forces arise from temporary fluctuations in electron density, leading to an induced dipole in neighboring molecules. Since fluorine molecules are small and have low mass, these van der Waals forces are relatively weak, resulting in a low boiling point as less energy is needed to overcome these forces during the phase transition from liquid to gas.

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