This question is about some elements in Group 7 and their compounds - AQA - A-Level Chemistry - Question 6 - 2022 - Paper 1
Question 6
This question is about some elements in Group 7 and their compounds.
Chlorine is added to some drinking water supplies to decrease the risk of people suffering from... show full transcript
Worked Solution & Example Answer:This question is about some elements in Group 7 and their compounds - AQA - A-Level Chemistry - Question 6 - 2022 - Paper 1
Step 1
State why the amount of chlorine added must be controlled.
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Answer
The amount of chlorine added must be controlled because excessive chlorine can be toxic and pose health risks, such as respiratory issues or skin irritation, as well as causing unpleasant tastes and odors in drinking water.
Step 2
Give an equation for the reaction of chlorine with water to form a solution containing two acids.
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The equation for the reaction is:
Cl2​+H2​O→HCl+HClO
Step 3
Explain, with reference to electrons, why this is a redox reaction.
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This is a redox (reduction-oxidation) reaction as chlorine undergoes reduction and oxidation simultaneously. In this reaction, one chlorine atom gains electrons to form chloride ions (Cl-) while the other loses electrons to form hypochlorous acid (HClO), showing a transfer of electrons.
Step 4
State the observation the student would make.
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The student would observe a brown solution or black solid forming, indicating the displacement reaction.
Step 5
Give an ionic equation for the reaction.
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The ionic equation for the reaction between chlorine and sodium iodide is:
Cl2​+2I−→2Cl−+I2​
Step 6
Give an equation for the formation of these sulfur-containing products.
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The equations for the formation of sulfur-containing products when sodium iodide reacts with sulfuric acid are:
H2​SO4​+2NaI→Na2​SO4​+I2​+H2​O
H2​SO4​+2NaI→Na2​SO4​+SO2​+2HI
Step 7
State the role of sulfuric acid in the formation of these products.
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In this reaction, sulfuric acid acts as an oxidizing agent, facilitating the oxidation of iodide ions (I-) to iodine (I2) or sulfur dioxide (SO2).
Step 8
Deduce the identity of the sodium halide.
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The identity of the sodium halide is sodium iodide (NaI).
Step 9
Suggest the identity of the gas.
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The identity of the gas is chlorine (Cl2).
Step 10
Give an ionic equation for the formation of this gas from the impurity.
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The ionic equation for the formation of chlorine gas from sodium iodide is:
2NaI+Cl2​→2Na++2Cl−+I2​
Step 11
Use your understanding of the electron pair repulsion theory to draw the shape of this ion.
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The shape of the ClF2- ion is linear with two bonded pairs and three lone pairs on the central chlorine atom.
Step 12
Explain why the ion has the shape you have drawn.
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The ClF2- ion has a linear shape due to the presence of three lone pairs of electrons that repel each other and the two bonded pairs of electrons, resulting in a geometry that minimizes repulsion.
Step 13
Suggest a value for the bond angle in the ion.
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The bond angle in the ClF2- ion is approximately 180 degrees.
Step 14
Give an equation for this reaction.
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The equation for the extraction of titanium from titanium(IV) chloride is: