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Nitration of 1.70 g of methyl benzoate (M_r = 136.0) produces methyl 3-nitrobenzoate (M_r = 181.0) - AQA - A-Level Chemistry - Question 29 - 2021 - Paper 3

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Nitration-of-1.70-g-of-methyl-benzoate-(M_r-=-136.0)-produces-methyl-3-nitrobenzoate-(M_r-=-181.0)-AQA-A-Level Chemistry-Question 29-2021-Paper 3.png

Nitration of 1.70 g of methyl benzoate (M_r = 136.0) produces methyl 3-nitrobenzoate (M_r = 181.0). The percentage yield is 65.0%. What mass, in g, of methyl 3-nit... show full transcript

Worked Solution & Example Answer:Nitration of 1.70 g of methyl benzoate (M_r = 136.0) produces methyl 3-nitrobenzoate (M_r = 181.0) - AQA - A-Level Chemistry - Question 29 - 2021 - Paper 3

Step 1

Calculate the number of moles of methyl benzoate

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Answer

To find the number of moles of methyl benzoate, use the formula: n = rac{m}{M_r} where:

  • m = 1.70 g (mass of methyl benzoate)
  • M_r = 136.0 g/mol (molar mass of methyl benzoate)

Calculating: n = rac{1.70}{136.0} = 0.0125 ext{ mol}

Step 2

Determine the theoretical yield of methyl 3-nitrobenzoate

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Since the reaction produces 1 mole of methyl 3-nitrobenzoate per mole of methyl benzoate, the theoretical moles of methyl 3-nitrobenzoate produced is also 0.0125 mol.
Now, calculate the mass of methyl 3-nitrobenzoate using: m=nimesMrm = n imes M_r where M_r = 181.0 g/mol.

Calculating: m=0.0125imes181.0=2.2625extgm = 0.0125 imes 181.0 = 2.2625 ext{ g}

Step 3

Adjust for percentage yield

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Answer

Since the percentage yield is 65.0%, the actual yield can be calculated as: extActualyield=extTheoreticalyieldimesextpercentageyield ext{Actual yield} = ext{Theoretical yield} imes ext{percentage yield}

Using the theoretical yield from the previous step: ext{Actual yield} = 2.2625 imes rac{65.0}{100} = 1.471625 ext{ g} Rounding to two decimal places, the mass of methyl 3-nitrobenzoate produced is approximately 1.47 g.

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