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In the electrochemical cell below, carbon electrodes are used during the electrolysis of a concentrated sodium chloride solution - NSC Physical Sciences - Question 9 - 2016 - Paper 2

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In the electrochemical cell below, carbon electrodes are used during the electrolysis of a concentrated sodium chloride solution. Gas X Gas Y Electrode P ... show full transcript

Worked Solution & Example Answer:In the electrochemical cell below, carbon electrodes are used during the electrolysis of a concentrated sodium chloride solution - NSC Physical Sciences - Question 9 - 2016 - Paper 2

Step 1

9.1 Is the reaction EXOTHERMIC or ENDOTHERMIC?

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Answer

The reaction is ENDOTHERMIC. This is because the process of electrolysis requires an input of energy to drive the non-spontaneous reaction.

Step 2

9.2 Is electrode P the ANODE or the CATHODE? Give a reason for the answer.

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Answer

Electrode P is the ANODE. This is because the anode is connected to the positive terminal of the battery, where oxidation occurs.

Step 3

9.3.1 NAME or FORMULA of gas X

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Answer

Gas X is Chlorine (Cl2).

Step 4

9.3.2 NAME or FORMULA of gas Y

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Answer

Gas Y is Hydrogen (H2).

Step 5

9.3.3 Reduction half-reaction

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Answer

The reduction half-reaction is:

2H2O(l)+2eH2(g)+2OH(aq)2H_2O(l) + 2e^- → H_2(g) + 2OH^-(aq)

Step 6

9.4 Is the solution in the cell ACIDIC or ALKALINE (BASIC) after completion of the reaction? Give a reason for the answer.

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Answer

The solution is ALKALINE (BASIC) after completion of the reaction. This is because hydroxide ions (OH⁻) are produced during the electrolysis process, leading to an increase in the pH.

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