In the electrochemical cell below, carbon electrodes are used during the electrolysis of a concentrated sodium chloride solution - NSC Physical Sciences - Question 9 - 2016 - Paper 2
Question 9
In the electrochemical cell below, carbon electrodes are used during the electrolysis of a concentrated sodium chloride solution.
Gas X Gas Y
Electrode P ... show full transcript
Worked Solution & Example Answer:In the electrochemical cell below, carbon electrodes are used during the electrolysis of a concentrated sodium chloride solution - NSC Physical Sciences - Question 9 - 2016 - Paper 2
Step 1
9.1 Is the reaction EXOTHERMIC or ENDOTHERMIC?
96%
114 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
The reaction is ENDOTHERMIC. This is because the process of electrolysis requires an input of energy to drive the non-spontaneous reaction.
Step 2
9.2 Is electrode P the ANODE or the CATHODE? Give a reason for the answer.
99%
104 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
Electrode P is the ANODE. This is because the anode is connected to the positive terminal of the battery, where oxidation occurs.
Step 3
9.3.1 NAME or FORMULA of gas X
96%
101 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
Gas X is Chlorine (Cl2).
Step 4
9.3.2 NAME or FORMULA of gas Y
98%
120 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
Gas Y is Hydrogen (H2).
Step 5
9.3.3 Reduction half-reaction
97%
117 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
The reduction half-reaction is:
2H2O(l)+2e−→H2(g)+2OH−(aq)
Step 6
9.4 Is the solution in the cell ACIDIC or ALKALINE (BASIC) after completion of the reaction? Give a reason for the answer.
97%
121 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
The solution is ALKALINE (BASIC) after completion of the reaction. This is because hydroxide ions (OH⁻) are produced during the electrolysis process, leading to an increase in the pH.