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Ammonium nitrate is an important fertiliser - NSC Physical Sciences - Question 10 - 2016 - Paper 2

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Ammonium nitrate is an important fertiliser. It is produced by reacting nitric acid with ammonia. Both nitric acid and ammonia are prepared on a large scale in indus... show full transcript

Worked Solution & Example Answer:Ammonium nitrate is an important fertiliser - NSC Physical Sciences - Question 10 - 2016 - Paper 2

Step 1

10.1 Write down the name of the industrial preparation of nitric acid.

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Answer

The name of the industrial preparation of nitric acid is the Ostwald process.

Step 2

10.2 The catalytic oxidation of ammonia is one of the steps in the process named in QUESTION 10.1. Write down the NAMES or FORMULAE of the TWO products formed in this step.

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Answer

The two products formed in the catalytic oxidation of ammonia are nitrogen monoxide (NO) and water (H₂O).

Step 3

10.3 Write down a balanced equation for the preparation of ammonium nitrate.

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Answer

The balanced equation for the preparation of ammonium nitrate is:

NH3+HNO3NH4NO3NH_3 + HNO_3 \rightarrow NH_4NO_3

Step 4

10.4 Calculate the mass, in kilogram, of ammonium nitrate that can be made from 6.8 x 10^4 kg of ammonia and excess nitric acid.

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Answer

To find the mass of ammonium nitrate produced from 6.8 x 10^4 kg of ammonia, we first need to convert the mass of ammonia to moles:

  • Molar mass of ammonia (NH₃) = 17 g/mol
  • Moles of ammonia = ( \frac{6.8 \times 10^4 ext{ kg} \times 10^3 ext{ g/kg}}{17 ext{ g/mol}} = 4.0 \times 10^6 ext{ mol} )

Since one mole of ammonia produces one mole of ammonium nitrate, we produce P 4.0 x 10^6 mol of ammonium nitrate.

Now, calculating the mass of ammonium nitrate:

  • Molar mass of ammonium nitrate (NH₄NO₃) = 80 g/mol
  • Mass = moles × molar mass = ( 4.0 \times 10^6 ext{ mol} \times 80 ext{ g/mol} = 3.2 \times 10^8 ext{ g} = 3.2 \times 10^5 ext{ kg} )

Step 5

10.5 Ammonium nitrate is often mixed with potassium chloride and ammonium phosphate. Give a reason why it is mixed with these compounds.

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Answer

Ammonium nitrate is mixed with potassium chloride and ammonium phosphate to create a balanced NPK (Nitrogen, Phosphorus, Potassium) fertiliser, which contains all three primary nutrients necessary for plant growth.

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