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Strong and weak acids and bases Simplified Revision Notes

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Strong and weak acids and bases

1. Ionisation of Acids and Bases

  • Acids and bases ionise in water to form ions.
  • The extent of ionisation determines whether they are strong or weak.
infoNote

Examples of Ionisation Reactions:

  • Strong acid: HCl(g)+H2O(l)H3O+(aq)+Cl(aq)HCl(g) + H_2O(l) \rightarrow H_3O^+(aq) + Cl^-(aq)

  • Weak acid: CH3COOH(l)+H2O(l)H3O+(aq)+CH3COO(aq)CH_3COOH(l) + H_2O(l) \rightleftharpoons H_3O^+(aq) + CH_3COO^-(aq)

2. Characteristics of Strong and Weak Acids

Strong AcidsWeak Acids
Completely ionise in waterPartially ionise in water
High [H3O+][H_3O^+]Low [H3O+][H_3O^+]
Low pH (closer to 1)Higher pH (closer to 7)
Good electrical conductorsPoor electrical conductors
High reaction rateLow reaction rate
Example: HCl,HNO3,H2SO4HCl, HNO₃, H₂SO₄Example: CH3COOH,H2CO3,H3PO4CH₃COOH, H₂CO₃, H₃PO₄

3. Characteristics of Strong and Weak Bases

Strong BasesWeak Bases
Completely dissociate in waterPartially ionise in water
High [OH][OH^-]Low [OH][OH^-]
High pH (closer to 14)Lower pH (closer to 7)
Good electrical conductorsPoor electrical conductors
Example: NaOH,KOHNaOH, KOHExample: NH3,Ca(OH)2NH₃, Ca(OH)₂

4. Understanding pH and Conductivity

  • pH indicates acidity or basicity:
    • pH<7AcidicpH < 7 → Acidic
    • pH=7NeutralpH = 7 → Neutral
    • pH>7BasicpH > 7 → Basic
  • Electrical conductivity depends on ion concentration:
    • More ionsHigher conductivity
    • Fewer ionsLower conductivity

5. Key Takeaways

  • Strong acids and bases ionise completely, producing more ions and having higher conductivity.
  • Weak acids and bases ionise partially, producing fewer ions and having lower conductivity.
  • Reaction rate and pH can be used to classify acids and bases in chemical reactions.
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