Dissociation Constants for Bases (HSC SSCE Chemistry): Flashcards

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Dissociation Constants for Bases
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KbK_b measures

How much a weak base splits apart in water

KbK_b equilibrium expression

[BH+][OH−][B]\frac{[\text{BH}^+][\text{OH}^-]}{[\text{B}]}

Larger KbK_b means

Stronger base, more dissociation occurs

Ka×KbK_a \times K_b equals

KwK_w (ion product of water)

KwK_w value at 25°C

1.0×10−141.0 \times 10^{-14}

KbK_b of ammonia (NH3\text{NH}_3)

1.8×10−51.8 \times 10^{-5}

Simplified KbK_b when [OH−]=[BH+][\text{OH}^-] = [\text{BH}^+]

[OH−]2[B]\frac{[\text{OH}^-]^2}{[\text{B}]}

Formula to find [OH−][\text{OH}^-] from pOH

[OH−]=10−pOH[\text{OH}^-] = 10^{-\text{pOH}}

Relationship between pH and pOH

pH+pOH=14\text{pH} + \text{pOH} = 14

Weak base concentration assumption at equilibrium

Equals initial concentration (dissociation negligible)

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