Self-Ionisation of Water (HSC SSCE Chemistry): Flashcards

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Self-Ionisation of Water
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Self-ionisation of water

Water reacting with itself to produce ions

Amphiprotic substance

Can act as both an acid and a base

Symbol for self-ionisation constant of water

KwK_w

KwK_w value at 298 K

1.0×10−141.0 \times 10^{-14} (mol L−1^{-1})2^2

KwK_w expression

Kw=[OH−][H3O+]K_w = [\text{OH}^-][\text{H}_3\text{O}^+]

[H3O+][\text{H}_3\text{O}^+] in pure water at 298 K

1.0×10−71.0 \times 10^{-7} mol L−1^{-1}

pH of pure water at 298 K

7 (neutral)

Acidic solution ion relationship

[H3O+]>[OH−][\text{H}_3\text{O}^+] > [\text{OH}^-]

Alkaline solution ion relationship

[H3O+]<[OH−][\text{H}_3\text{O}^+] < [\text{OH}^-]

Formula to find [H3O+][\text{H}_3\text{O}^+] from [OH−][\text{OH}^-]

[H3O+]=Kw[OH−][\text{H}_3\text{O}^+] = \frac{K_w}{[\text{OH}^-]}

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