Buffers (HSC SSCE Chemistry): Flashcards

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Buffers
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Buffer definition

Weak acid + conjugate base that resists pH changes

How buffers counteract pH changes

Equilibrium shifts via Le Chatelier's principle

Condition for maximum buffer capacity

Equal moles of weak acid and conjugate base

pH when [A−]=[HA][\text{A}^-] = [\text{HA}]

pH equals pKa\text{p}K_a

Effective buffer ratio [A−]/[HA][\text{A}^-]/[\text{HA}] range

Between 110\frac{1}{10} and 1010

Seawater buffer system ions

Bicarbonate (HCO3−\text{HCO}_3^-) and carbonate (CO32−\text{CO}_3^{2-})

Natural seawater pH range

8.0−8.38.0-8.3

Human blood pH range

7.35−7.457.35-7.45

Main buffer in blood

H2CO3\text{H}_2\text{CO}_3/HCO3−\text{HCO}_3^- system

Main form CO2\text{CO}_2 transported in blood

Hydrogen carbonate ion (HCO3−\text{HCO}_3^-)

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