Primary Standard Solutions (HSC SSCE Chemistry): Flashcards

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Primary Standard Solutions
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Primary standard definition

Substance for solution with accurately known concentration

Accuracy in chemistry

Number of significant figures in a measurement

Why primary stds need large molar mass

Larger masses reduce percentage error, improving accuracy

Why primary stds must be anhydrous

Water of hydration varies with humidity, altering composition

Why primary stds must be stable in air

Won't react with O2O_2, CO2CO_2, or atmospheric moisture

Most common primary std in school labs

Anhydrous sodium carbonate (Na2CO3Na_2CO_3)

Second common primary std

Sodium hydrogen carbonate (NaHCO3NaHCO_3)

Why can't NaOHNaOH be a primary std?

Hygroscopic and reacts with CO2CO_2 from air

Why not use Na2CO3⋅10H2ONa_2CO_3 \cdot 10H_2O?

Contains water of hydration that varies with humidity

Why rinse beaker during preparation?

To transfer all weighed substance to volumetric flask

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