Infrared Spectroscopy (HSC SSCE Chemistry): Flashcards

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Infrared Spectroscopy
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IR spectroscopy identifies

Chemical bonds or functional groups in a compound

Two types of molecular vibrations in IR

Stretching and bending

Diatomic molecules not detected by IR

O2\text{O}_2 and N2\text{N}_2

IR wavenumber range (cm−1\text{cm}^{-1})

4000 to 500 cm−1\text{cm}^{-1}

IR spectrum y-axis shows

Percentage transmittance

Fingerprint region range (cm−1\text{cm}^{-1})

1500-500 cm−1\text{cm}^{-1}

C—H\text{C—H} bond absorption range (cm−1\text{cm}^{-1})

2800-3000 cm−1\text{cm}^{-1}

Alcohol —OH\text{—OH} absorption range (cm−1\text{cm}^{-1})

3000-3500 cm−1\text{cm}^{-1}, broad & strong

C=O\text{C=O} carbonyl absorption (cm−1\text{cm}^{-1})

Around 1700 cm−1\text{cm}^{-1}

Carboxylic acid IR characteristics

Broad —OH\text{—OH} (~3000) + C=O\text{C=O} (~1700 cm−1\text{cm}^{-1})

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