Mass Spectroscopy (HSC SSCE Chemistry): Flashcards

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Mass Spectroscopy
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Energy type used in mass spectroscopy

High-energy electrons

Parent molecular ion peak indicates

Molar mass of the compound

Base peak definition

Tallest peak, 100% relative abundance

Molecular ion

Molecule that lost one electron, +1 charge

Why neutral radicals not detected

Only cations detected in mass spectrometry

Fragment at m/z = 15

CH3+CH_3^+ (methyl)

Fragment at m/z = 17

OH (hydroxyl)

Fragment at m/z = 45

COOH or OCH2CH3OCH_2CH_3

Ion deflection factors in mass spec

Mass (m) and charge (z)

Mass spec vs other spectroscopy

Breaks molecules apart vs just interacting

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