Two Basic Drives (HSC SSCE Chemistry): Flashcards

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Two Basic Drives
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Energy drive

Nature's tendency to move from high to low energy states

Entropy (SS)

Measure of randomness, chaos, or disorder in a substance

Entropy drive

Nature's tendency towards increased chaos/randomness

Entropy order for states of matter

Solid < Liquid < Gas

If entropy drive is positive, ΔS\Delta S is...

Positive (same direction)

If energy drive is forward, ΔH\Delta H is...

Negative (opposite relationship)

Both drives forward means reaction...

Always occurs spontaneously

Both drives backward means reaction...

Never occurs spontaneously

Gas production effect on entropy

Greatly increases entropy (ΔS\Delta S positive)

Dissolution of solid in solvent effect on entropy

Increases entropy

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