Dissociation Constants for Bases (HSC SSCE Chemistry): Quizzes

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Dissociation Constants for Bases
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What does the base dissociation constant (KbK_b) measure?

Extent of weak base splitting in water

What is the correct equilibrium expression for KbK_b for a general base B?

Kb=[BH+][OH−][B]K_b = \frac{[\text{BH}^+][\text{OH}^-]}{[\text{B}]}

How does a larger KbK_b value relate to base strength?

Larger KbK_b indicates a stronger base

What percentage of strong bases like NaOH dissociate in water?

Nearly 100%

For ammonia equilibrium, what is the relationship between [OH−][\text{OH}^-] and [NH4+][\text{NH}_4^+]?

[OH−]=[NH4+][\text{OH}^-] = [\text{NH}_4^+]

What is the relationship between KaK_a and KbK_b for a conjugate acid-base pair?

Ka×Kb=KwK_a \times K_b = K_w

For strong bases, how do you find [OH−][\text{OH}^-] from pOH?

[OH−]=10−pOH[\text{OH}^-] = 10^{-\text{pOH}}

Which assumption is made when calculating with weak bases?

Equilibrium [B]≈[\text{B}] \approx initial [B][\text{B}]

From the table, which base is strongest: phosphate ion or aniline?

Phosphate ion (Kb=5.9×10−3K_b = 5.9 \times 10^{-3})

If Ka=5.6×10−10K_a = 5.6 \times 10^{-10} for NH4+\text{NH}_4^+, what is KbK_b for NH3\text{NH}_3?

1.8×10−51.8 \times 10^{-5}

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