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A 0.10 M standard solution of hydrochloric acid (HCl) was used to find the concentration of a sodium hydroxide (NaOH) solution by titration - Leaving Cert Chemistry - Question 2 - 2007

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A 0.10 M standard solution of hydrochloric acid (HCl) was used to find the concentration of a sodium hydroxide (NaOH) solution by titration. The piece of equipment A... show full transcript

Worked Solution & Example Answer:A 0.10 M standard solution of hydrochloric acid (HCl) was used to find the concentration of a sodium hydroxide (NaOH) solution by titration - Leaving Cert Chemistry - Question 2 - 2007

Step 1

Name the piece of equipment A.

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Answer

The piece of equipment A is a burette.

Step 2

Which of the two solutions is usually measured using the piece of equipment labelled A?

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Answer

The hydrochloric acid (HCl) solution is usually measured using the piece of equipment labelled A.

Step 3

Name the piece of equipment used to measure the second solution used in the titration.

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Answer

The piece of equipment used to measure the second solution is a pipette.

Step 4

Describe the correct procedure for rinsing and filling A.

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Answer

To properly rinse and fill the burette:

  1. Rinse the burette with distilled water followed by a small amount of the hydrochloric acid solution to prevent contamination.
  2. Ensure the burette is held upright and the tap is closed before filling.
  3. Fill the burette above the zero mark, then open the tap to allow the liquid to drain until the bottom meniscus is on the zero mark.

Step 5

Why is it preferable to use a filter (labelled B in the diagram) rather than your hand when filling A?

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Answer

Using a filter prevents contamination of the solution and ensures the liquid flows smoothly into the burette without spilling or introducing air bubbles.

Step 6

State one precaution you would take when transferring the liquid measured in A to the titration flask to ensure that the correct volume was transferred.

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Answer

One precaution is to allow the liquid to drain under gravity without touching the side of the flask to avoid liquid retention inside the burette.

Step 7

Name a suitable indicator for this titration. What colour change was observed in the titration flask at the end point?

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Answer

A suitable indicator for this titration is methyl orange. The colour change observed at the end point was from yellow to red.

Step 8

The balanced equation for the titration reaction.

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Answer

The balanced equation for the titration reaction is:

extHCl+extNaOHightarrowextNaCl+extH2extO ext{HCl} + ext{NaOH} ightarrow ext{NaCl} + ext{H}_2 ext{O}

Step 9

Calculate the concentration of the sodium hydroxide solution in moles per litre.

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Answer

To calculate the concentration, use the formula:

C1V1=C2V2C_1V_1 = C_2V_2

Substituting the values:

0.10extMimes27.5extcm3=C2imes25.0extcm30.10 ext{ M} imes 27.5 ext{ cm}^3 = C_2 imes 25.0 ext{ cm}^3

Solving for C2C_2 gives:

C_2 = rac{0.10 imes 27.5}{25.0} = 0.11 ext{ M}

Hence, the concentration of the sodium hydroxide solution is 0.11 M.

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