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The apparatus drawn was used in a student experiment to measure the heat of reaction (ΔH) for the reaction between 1.0 M hydrochloric acid (HCl) solution and 1.0 M sodium hydroxide (NaOH) solution - Leaving Cert Chemistry - Question 3 - 2007

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The apparatus drawn was used in a student experiment to measure the heat of reaction (ΔH) for the reaction between 1.0 M hydrochloric acid (HCl) solution and 1.0 M s... show full transcript

Worked Solution & Example Answer:The apparatus drawn was used in a student experiment to measure the heat of reaction (ΔH) for the reaction between 1.0 M hydrochloric acid (HCl) solution and 1.0 M sodium hydroxide (NaOH) solution - Leaving Cert Chemistry - Question 3 - 2007

Step 1

What is meant by heat of reaction?

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Answer

The heat of reaction, or ΔH, refers to the energy change that occurs when one mole of reactant is completely converted to products according to a balanced chemical equation.

Step 2

How do the temperature measurements taken during the experiment provide evidence that the reaction between HCl and NaOH is exothermic?

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Answer

During the experiment, the temperature of the reaction mixture increases, indicating that heat is released. This increase in temperature suggests that the reaction is exothermic, as energy is being transferred from the reaction mixture to the surroundings.

Step 3

What is the advantage of using a cup made from polystyrene?

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Answer

Polystyrene is a good insulator, which minimizes heat loss to the environment during the reaction. This helps in obtaining more accurate temperature readings since it reduces the error due to external temperature changes.

Step 4

How would you have obtained a reasonably accurate value for the change in temperature?

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Answer

To achieve accurate results, allow temperature equalisation before starting the experiment. Use a calibrated thermometer to measure initial temperatures accurately. Stir the solution thoroughly and quickly record the highest temperature reached to ensure accurate temperature data.

Step 5

Calculate (i) the number of moles of hydrochloric acid (HCl) in 50 cm³ of 1.0 M hydrochloric acid.

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Answer

The number of moles can be calculated using the formula:

ext{moles} = rac{ ext{Volume (L)} imes ext{Concentration (mol/L)}}{1}

For 50 cm³ (or 0.050 L) of 1.0 M solution:

extmoles=0.050imes1.0=0.05extmoles ext{moles} = 0.050 imes 1.0 = 0.05 ext{ moles}

Step 6

Calculate (ii) the heat in kJ which would be produced if a solution containing 1 mole of hydrochloric acid reacted fully with sodium hydroxide.

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Answer

Given that 2.8 kJ of heat is produced when 0.05 moles of HCl react, the heat produced when 1 mole reacts is calculated as follows:

ext{Heat per mole} = rac{2.8 ext{ kJ}}{0.05 ext{ moles}} = 56 ext{ kJ}

Step 7

What term is used for the reaction between an acid and a base resulting in the production of a salt and water?

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Answer

The term used for this reaction is 'neutralisation.' In a neutralisation reaction, an acid reacts with a base to form a salt and water.

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