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A 0.06 M standard solution of sodium carbonate was made up by weighing out X grams of anhydrous sodium carbonate (Na2CO3), dissolving it in deionised water, and making the solution carefully up to the mark in a suitable 1 litre flask - Leaving Cert Chemistry - Question 2 - 2006

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A 0.06 M standard solution of sodium carbonate was made up by weighing out X grams of anhydrous sodium carbonate (Na2CO3), dissolving it in deionised water, and maki... show full transcript

Worked Solution & Example Answer:A 0.06 M standard solution of sodium carbonate was made up by weighing out X grams of anhydrous sodium carbonate (Na2CO3), dissolving it in deionised water, and making the solution carefully up to the mark in a suitable 1 litre flask - Leaving Cert Chemistry - Question 2 - 2006

Step 1

Name the piece of equipment A used to make up 1 litre of the Na2CO3 solution.

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Answer

The piece of equipment A is a volumetric flask.

Step 2

What should be done with A and its contents immediately after bringing the solution up to the 1 litre mark with deionised water? Why is this important?

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Answer

A should be inverted. This is important to ensure that the solution is well mixed and homogeneous.

Step 3

What is meant by a standard solution?

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Answer

A standard solution is a solution whose concentration is known with high accuracy, which can be used for titration and calibration purposes.

Step 4

Calculate the mass (X) of sodium carbonate (Na2CO3) required to make 1 litre of a 0.06 M solution.

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Answer

To find the mass, we use the formula:

X=MimesVimesMwX = M imes V imes M_w

Where:

  • M = molarity (0.06 M)
  • V = volume (1 L) = 1000 cm³
  • M_w = molar mass of Na2CO3 = 106 g/mol

Substituting the values:

X=0.06imes1000imes106=6.36extgX = 0.06 imes 1000 imes 106 = 6.36 ext{ g}

Step 5

Name the pieces of equipment B and C used in the titration.

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Answer

B is a pipette and C is a burette.

Step 6

Name a suitable indicator for this titration and state the colour change at the end point.

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Answer

A suitable indicator is methyl orange. The colour changes from yellow to pink/orange to red.

Step 7

What should be done with the conical flask and its contents during the titration in order to ensure accuracy?

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Answer

The walls of the conical flask should be washed down with deionised water and swirled to ensure that all contents are mixed properly.

Step 8

Calculate the concentration of the hydrochloric acid solution in moles per litre.

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Answer

Using the titration data:

rac{25.0 ext{ cm}^3 imes 0.06 ext{ M}}{V_{ ext{HCl}}} = rac{30.0 ext{ cm}^3 imes C_{ ext{HCl}}}{1}

Letting the volume of HCl be the remaining volume, we deduce:

Based on stoichiometry, if 25.0 cm³ of Na2CO3 was required, the concentration of the HCl solution would be calculated to be:

CextHCl=0.10extMC_{ ext{HCl}} = 0.10 ext{ M}

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