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5. (a) State two assumptions of Dalton's atomic theory of 1808 - Leaving Cert Chemistry - Question 5 - 2010

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5. (a) State two assumptions of Dalton's atomic theory of 1808. (b) The electron was the first of the sub-atomic particles to be discovered. It was identified in ex... show full transcript

Worked Solution & Example Answer:5. (a) State two assumptions of Dalton's atomic theory of 1808 - Leaving Cert Chemistry - Question 5 - 2010

Step 1

State two assumptions of Dalton's atomic theory of 1808.

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Answer

  1. All matter is composed of very small, indivisible particles known as atoms.
  2. All atoms of a given element are identical in mass and properties.

Step 2

Name the scientist (i) who, about 1897, measured the ratio of charge to mass of the electron, e/m,

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Answer

J.J. Thomson.

Step 3

Name the scientist (ii) who, about 1910, proved that the electrons in an atom reside in an electron cloud surrounding a small dense positive central nucleus.

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Answer

Ernest Rutherford.

Step 4

Name the scientist (iii) who, about 1911, measured the charge on the electron, e.

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Answer

Robert Millikan.

Step 5

Outline Bohr's atomic theory based on the hydrogen emission spectrum.

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Answer

  1. The electron in a hydrogen atom occupies fixed energy levels (discrete energies).
  2. An electron in an energy level does not radiate energy.
  3. The electron occupies the lowest energy level available or ground state.
  4. The electron can move to a higher energy level if it receives an amount of energy (photon of energy).
  5. The photon emitted when transitioning back to lower energy levels must match the energy difference between the levels.

Step 6

State two limitations of Bohr's theory that led to its modification.

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Answer

  1. Bohr's theory did not account for atoms with more than one electron.
  2. It did not take wave-particle duality into account.

Step 7

Define atomic orbital.

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Answer

An atomic orbital is a region of space around the nucleus of an atom where there is a 99% probability of finding an electron.

Step 8

State the shape of the p-orbital.

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Answer

The p-orbital has a dumbbell shape.

Step 9

State the maximum number of electrons that can be accommodated in a p-orbital.

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Answer

The maximum number of electrons that can be accommodated in a p-orbital is 6.

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