In an experiment to measure the heat of reaction (\Delta H) for the reaction between hydrochloric acid (HCl) and sodium hydroxide (NaOH), 100 cm³ of 2M HCl were added to 100 cm³ of 2M NaOH in the apparatus shown in the diagram - Leaving Cert Chemistry - Question 3 - 2012
Question 3
In an experiment to measure the heat of reaction (\Delta H) for the reaction between hydrochloric acid (HCl) and sodium hydroxide (NaOH), 100 cm³ of 2M HCl were adde... show full transcript
Worked Solution & Example Answer:In an experiment to measure the heat of reaction (\Delta H) for the reaction between hydrochloric acid (HCl) and sodium hydroxide (NaOH), 100 cm³ of 2M HCl were added to 100 cm³ of 2M NaOH in the apparatus shown in the diagram - Leaving Cert Chemistry - Question 3 - 2012
Step 1
Explain the underlining term.
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Answer
The term refers to the heat change when one mole of HCl reacts completely with one mole of NaOH in the reaction. This indicates that the reaction is a neutralization process where these reactants produce salt (NaCl) and water (H₂O), resulting in a temperature change.
Step 2
What is an exothermic reaction?
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Answer
An exothermic reaction is a type of chemical reaction where heat is released into the surroundings as products form. This is shown by a decrease in temperature of the reaction mixture, and the net energy change (\Delta H) is negative.
Step 3
Indicate two features of the apparatus that help to minimise heat loss to the surroundings.
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Answer
Polystyrene Cup: The polystyrene cup is a poor conductor of heat, which helps to reduce heat loss.
Cover: The cover on the cup provides insulation by preventing heat from escaping upward, thus retaining more heat within the system.
Step 4
Calculate the number of moles of HCl in 100 cm³ of 2M HCl.
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Answer
The calculation for the number of moles is as follows:
Number of moles = concentration (mol/dm³) × volume (dm³)
Converting 100 cm³ to dm³ gives:
100 cm³ = 0.1 dm³
Therefore,:
Number of moles of HCl = 2 mol/dm³ × 0.1 dm³ = 0.2 moles.
Step 5
How many kilojoules of heat would be produced if 1 mole of HCl reacted fully with NaOH?
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Therefore, for 1 mole of HCl, it produces 5.7 kJ of heat.
Step 6
What is the heat of reaction (\Delta H) for this reaction?
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Answer
The heat of reaction (\Delta H) for this reaction is therefore -57 kJ mol⁻¹, indicating that the process is exothermic.
Step 7
The symbol shown on the right is found on bottles of hydrochloric acid. What does this symbol signify?
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The symbol signifies that hydrochloric acid is a corrosive substance, indicating that it can cause severe chemical burns or destruction of tissues upon contact.
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