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In an experiment to measure the heat of reaction (\Delta H) for the reaction between hydrochloric acid (HCl) and sodium hydroxide (NaOH), 100 cm³ of 2M HCl were added to 100 cm³ of 2M NaOH in the apparatus shown in the diagram - Leaving Cert Chemistry - Question 3 - 2012

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In an experiment to measure the heat of reaction (\Delta H) for the reaction between hydrochloric acid (HCl) and sodium hydroxide (NaOH), 100 cm³ of 2M HCl were adde... show full transcript

Worked Solution & Example Answer:In an experiment to measure the heat of reaction (\Delta H) for the reaction between hydrochloric acid (HCl) and sodium hydroxide (NaOH), 100 cm³ of 2M HCl were added to 100 cm³ of 2M NaOH in the apparatus shown in the diagram - Leaving Cert Chemistry - Question 3 - 2012

Step 1

Explain the underlining term.

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Answer

The term refers to the heat change when one mole of HCl reacts completely with one mole of NaOH in the reaction. This indicates that the reaction is a neutralization process where these reactants produce salt (NaCl) and water (H₂O), resulting in a temperature change.

Step 2

What is an exothermic reaction?

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Answer

An exothermic reaction is a type of chemical reaction where heat is released into the surroundings as products form. This is shown by a decrease in temperature of the reaction mixture, and the net energy change (\Delta H) is negative.

Step 3

Indicate two features of the apparatus that help to minimise heat loss to the surroundings.

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Answer

  1. Polystyrene Cup: The polystyrene cup is a poor conductor of heat, which helps to reduce heat loss.
  2. Cover: The cover on the cup provides insulation by preventing heat from escaping upward, thus retaining more heat within the system.

Step 4

Calculate the number of moles of HCl in 100 cm³ of 2M HCl.

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Answer

The calculation for the number of moles is as follows:

Number of moles = concentration (mol/dm³) × volume (dm³)

Converting 100 cm³ to dm³ gives:

100 cm³ = 0.1 dm³

Therefore,:

Number of moles of HCl = 2 mol/dm³ × 0.1 dm³ = 0.2 moles.

Step 5

How many kilojoules of heat would be produced if 1 mole of HCl reacted fully with NaOH?

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Answer

To find the heat produced for 1 mole of HCl:

  1. Heat produced from 0.2 moles of reaction: 1.14 kJ
  2. Heat per mole = \frac{1.14 ext{ kJ}}{0.2 ext{ moles}} = 5.7 ext{ kJ/mol}

Therefore, for 1 mole of HCl, it produces 5.7 kJ of heat.

Step 6

What is the heat of reaction (\Delta H) for this reaction?

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Answer

The heat of reaction (\Delta H) for this reaction is therefore -57 kJ mol⁻¹, indicating that the process is exothermic.

Step 7

The symbol shown on the right is found on bottles of hydrochloric acid. What does this symbol signify?

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Answer

The symbol signifies that hydrochloric acid is a corrosive substance, indicating that it can cause severe chemical burns or destruction of tissues upon contact.

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