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A group of students prepared ethano l (C2H5OH) by slowly adding a mixture of ethanol (C2H5OH) and an oxidising agent in water, to hot aqueous sulphuric acid - Leaving Cert Chemistry - Question 1 - 2005

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Question 1

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A group of students prepared ethano l (C2H5OH) by slowly adding a mixture of ethanol (C2H5OH) and an oxidising agent in water, to hot aqueous sulphuric acid. The app... show full transcript

Worked Solution & Example Answer:A group of students prepared ethano l (C2H5OH) by slowly adding a mixture of ethanol (C2H5OH) and an oxidising agent in water, to hot aqueous sulphuric acid - Leaving Cert Chemistry - Question 1 - 2005

Step 1

Identify this solid and state its purpose.

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Answer

The solid material is identified as pumice stones or porcelain pieces. Its purpose is to prevent bumping during the reaction.

Step 2

Identify a suitable oxidising agent for this preparation.

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Answer

A suitable oxidising agent for this preparation is sodium dichromate or potassium permanganate.

Step 3

What is the colour of the mixture in the dropping funnel at the start?

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Answer

The colour of the mixture in the dropping funnel at the start is yellow, matching the oxidising agent used.

Step 4

What is the colour of the mixture in the reaction flask as the reaction proceeds?

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Answer

The colour of the mixture in the reaction flask changes to green as the reaction proceeds, due to the reduction of the permanganate.

Step 5

Why is it important to distill off the ethanol as it is produced?

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Answer

It is important to distill off the ethanol as it is produced to prevent excessive oxidation and avoid the production of ethanoic acid.

Step 6

Why is it not necessary to keep heating the reaction flask during the addition?

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Answer

It is not necessary to keep heating the reaction flask during the addition because the reaction is exothermic, generating sufficient heat.

Step 7

Why is the receiving vessel cooled in ice-water?

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Answer

The receiving vessel is cooled in ice-water to condense the ethanol vapor effectively and to maintain a lower temperature.

Step 8

What colour is the solid produced when a mixture containing a few drops of Fehling’s solutions (No 1 and No 2) and ethanol is heated?

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Answer

The solid produced is brick red, indicating the presence of copper(I) oxide.

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