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Nitric acid and its salts contain the nitrite ion (NO₂⁻) - Leaving Cert Chemistry - Question (d) - 2014

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Question (d)

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Nitric acid and its salts contain the nitrite ion (NO₂⁻). Describe in detail how you could test for the presence of the nitrate anion in aqueous solution.

Worked Solution & Example Answer:Nitric acid and its salts contain the nitrite ion (NO₂⁻) - Leaving Cert Chemistry - Question (d) - 2014

Step 1

Add freshly-prepared iron(II) sulfate (FeSO₄) solution

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Answer

Begin the test by adding a few drops of freshly-prepared iron(II) sulfate solution to a clean test tube. This compound will facilitate the formation of a distinct reaction product if nitrate ions are present.

Step 2

Trickle concentrated sulfuric acid (H₂SO₄) dropwise

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Answer

Carefully trickle concentrated sulfuric acid down the side of the test tube containing the iron(II) sulfate solution. Keep the test tube in a slanted position to allow the acid to form a distinct layer above the iron(II) sulfate solution without mixing them.

Step 3

Observe results for formation of brown ring

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Answer

After adding the sulfuric acid, observe the junction of the two liquids. A brown ring should form at the interface if the nitrate ions are present. This reaction indicates the successful identification of nitrate anions.

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