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A mass of 6.35 g of pure copper was reacted with an excess of warm concentrated sulfuric acid to produce copper(II) sulfate, water and sulfur dioxide according to the following equation: Cu + 2H₂SO₄ → CuSO₄ + 2H₂O + SO₂ - Leaving Cert Chemistry - Question a - 2010

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A mass of 6.35 g of pure copper was reacted with an excess of warm concentrated sulfuric acid to produce copper(II) sulfate, water and sulfur dioxide according to th... show full transcript

Worked Solution & Example Answer:A mass of 6.35 g of pure copper was reacted with an excess of warm concentrated sulfuric acid to produce copper(II) sulfate, water and sulfur dioxide according to the following equation: Cu + 2H₂SO₄ → CuSO₄ + 2H₂O + SO₂ - Leaving Cert Chemistry - Question a - 2010

Step 1

How many moles of copper were used? How many moles of sulfuric acid were used up?

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Answer

To find the number of moles of copper used, we use the formula:

n=mMn = \frac{m}{M}

where:

  • nn is the number of moles,
  • mm is the mass (6.35 g),
  • MM is the molar mass of copper (Cu) which is approximately 63.5 g/mol.

Calculating:

nCu=6.35 g63.5 g/mol=0.1 molesn_{Cu} = \frac{6.35 \text{ g}}{63.5 \text{ g/mol}} = 0.1 \text{ moles}

Since the balanced equation shows that 1 mole of Cu reacts with 2 moles of H₂SO₄:

nH2SO4=2×nCu=2×0.1=0.2 molesn_{H₂SO₄} = 2 \times n_{Cu} = 2 \times 0.1 = 0.2 \text{ moles}

Step 2

What mass of water was produced in the reaction?

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Answer

From the balanced equation, 2 moles of water (H₂O) are produced for every 1 mole of copper reacted. Thus:

nH2O=2×nCu=2×0.1=0.2 molesn_{H₂O} = 2 \times n_{Cu} = 2 \times 0.1 = 0.2 \text{ moles}

Now, to find the mass of water produced, we calculate:

mH2O=nH2O×MH2Om_{H₂O} = n_{H₂O} \times M_{H₂O} where the molar mass of water (H₂O) is approximately 18 g/mol:

mH2O=0.2 moles×18 g/mol=3.6extgm_{H₂O} = 0.2 \text{ moles} \times 18 \text{ g/mol} = 3.6 ext{ g}

Step 3

What volume of sulfur dioxide (at s.t.p.) was produced in the reaction? How many molecules did this volume contain?

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Answer

From the balanced equation, 1 mole of sulfur dioxide (SO₂) is produced for every mole of copper reacted. Therefore:

nSO2=nCu=0.1 molesn_{SO₂} = n_{Cu} = 0.1 \text{ moles}

The volume of gas at standard temperature and pressure (s.t.p.) is measured as 22.4 liters per mole:

VSO2=nSO2×22.4 L/mol=0.1 moles×22.4 L/mol=2.24 litersV_{SO₂} = n_{SO₂} \times 22.4 \text{ L/mol} = 0.1 \text{ moles} \times 22.4 \text{ L/mol} = 2.24 \text{ liters}

To find the number of molecules in this volume, we use Avogadro's number (6.022×10236.022 \times 10^{23} molecules/mol):

Number of molecules=nSO2×6.022×1023=0.1 moles×6.022×10236×1022 molecules\text{Number of molecules} = n_{SO₂} \times 6.022 \times 10^{23} = 0.1 \text{ moles} \times 6.022 \times 10^{23} \approx 6 \times 10^{22} \text{ molecules}

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