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What is a crystal? Crystals may be classified as ionic, molecular, metallic, and covalent macromolecular - Leaving Cert Chemistry - Question B - 2019

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What is a crystal? Crystals may be classified as ionic, molecular, metallic, and covalent macromolecular. To which of these categories does crystalline iodine (I₂) ... show full transcript

Worked Solution & Example Answer:What is a crystal? Crystals may be classified as ionic, molecular, metallic, and covalent macromolecular - Leaving Cert Chemistry - Question B - 2019

Step 1

What is a crystal?

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Answer

A crystal is defined as a regular (repeating) pattern (lattice) of atoms, ions, molecules, or particles arranged in an orderly manner. This structure allows for unique physical and chemical properties.

Step 2

To which of these categories does crystalline iodine (I₂) belong? Justify your answer.

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Answer

Crystalline iodine (I₂) belongs to the molecular category. This is because iodine molecules, which occupy lattice points, are held together by weak intermolecular forces such as van der Waals forces, resulting in its relatively low melting point.

Step 3

What technique was used by Dorothy Hodgkin to determine the molecular structure of vitamin B₁₂?

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Dorothy Hodgkin used x-ray crystallography, also known as x-ray analysis or x-ray diffraction, as the technique to determine the molecular structure of vitamin B₁₂.

Step 4

Explain, in terms of its structure and bonding, why graphite can be used as a lubricant.

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Answer

Graphite consists of layers of carbon atoms that are strongly bonded covalently in each layer, while the layers themselves are held together by weaker van der Waals forces. This allows the layers to slide over each other easily, making graphite effective as a lubricant.

Step 5

Explain, with reference to the structure of metallic crystals, why silver (Ag) is an excellent electrical conductor.

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Answer

Silver consists of positively charged ions within a structure where valence (outer) electrons are delocalized. These free-moving electrons act as charge carriers, allowing silver to conduct electricity exceptionally well.

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