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What is a crystal? Crystals may be classified as ionic, molecular, metallic, and covalent macromolecular - Leaving Cert Chemistry - Question B - 2019

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What is a crystal? Crystals may be classified as ionic, molecular, metallic, and covalent macromolecular. Which of these categories does crystalline iodine (I₂) b... show full transcript

Worked Solution & Example Answer:What is a crystal? Crystals may be classified as ionic, molecular, metallic, and covalent macromolecular - Leaving Cert Chemistry - Question B - 2019

Step 1

What is a crystal?

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Answer

A crystal is defined as a regular (repeating) pattern (lattice) of atoms, molecules, or particles. This orderly arrangement facilitates specific properties such as symmetry and a defined geometric shape.

Step 2

Which of these categories does crystalline iodine (I₂) belong? Justify your answer.

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Answer

Crystalline iodine (I₂) belongs to the category of molecular crystals. This is because iodine molecules occupy lattice points and are held together by weak intermolecular forces, such as van der Waals forces, leading to a low melting point.

Step 3

What technique was used by Dorothy Hodgkin to determine the molecular structure of vitamin B₁₂?

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Answer

Dorothy Hodgkin used X-ray crystallography, also known as x-ray scattering or x-ray analysis, to determine the molecular structure of vitamin B₁₂. This technique leverages the diffraction of X-rays through the crystal lattice to reveal the arrangement of atoms within the molecule.

Step 4

Explain, in terms of its structure and bonding, why graphite can be used as a lubricant.

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Answer

Graphite consists of layers of carbon atoms that are strongly bonded together within each layer by covalent bonds. However, the layers themselves are held together by weak van der Waals forces. This allows the layers to slide over each other easily, making graphite an effective lubricant.

Step 5

Explain, with reference to the structure of metallic crystals, why silver (Ag) is an excellent electrical conductor.

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Answer

In metallic crystals like silver, positively charged silver ions are arranged in a lattice structure, with valence (outer) electrons being delocalized. These delocalized electrons are free to move throughout the crystal, allowing silver to conduct electricity effectively due to the mobility of these charge carriers.

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