Study the reaction scheme and answer the questions below - Leaving Cert Chemistry - Question 8 - 2020
Question 8
Study the reaction scheme and answer the questions below.
$$C_2H_4$$
(i) Identify in the scheme (i) a substitution reaction, (ii) an addition reaction,
(iii) an el... show full transcript
Worked Solution & Example Answer:Study the reaction scheme and answer the questions below - Leaving Cert Chemistry - Question 8 - 2020
Step 1
Identify in the scheme (i) a substitution reaction, (ii) an addition reaction, (iii) an elimination reaction.
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Answer
Substitution Reaction: The transformation from C2H5Cl to C2H4 involving the replacement of chlorine by hydrogen in the presence of a suitable reagent.
Addition Reaction: The conversion from C2H4 to C2H6, where additional hydrogen is added to the double bond of ethene.
Elimination Reaction: The conversion of C2H4 to C2H2, which involves the removal of a small molecule, resulting in the formation of a double bond.
Step 2
What reagent and catalyst can be used in conversion 1?
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In conversion 1, the reagent used is hydrogen (H2) and the catalyst can be nickel (Ni), palladium (Pd), or platinum (Pt).
Step 3
Copy the structure of ethanol and identify clearly the bonds formed during conversion 1.
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The structure of ethanol is as follows:
H H
| |
H - C - C - O - H
| |
H H
In conversion 1, the bonds formed include:
The C-H bonds are created when hydrogen is added to the carbon atoms.
The C-O bond is present in the ethanol structure.
Step 4
Identify an organic substance in the scheme that is highly soluble in water. Justify your answer.
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The organic substance that is highly soluble in water is ethanol (C2H5OH). This is due to the presence of the hydroxyl (−OH) group which can form hydrogen bonds with water molecules, enhancing its solubility.
Step 5
Identify compound X.
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Compound X is identified as chloroethene (monochloroethene or vinyl chloride, C2H3Cl).
Step 6
How does the geometry around the carbon atoms change during conversion 7?
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During conversion 7, the geometry changes from trigonal planar around the carbon atom in chloroethene to tetrahedral when it converts to ethane, following the saturation of the double bond.
Step 7
Draw the structure of two repeating units of the polymer PVC.
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The repeating unit of polyvinyl chloride (PVC) can be represented as:
Cl H H H
| | |
--C--C--C--C--
| | | |
H H Cl Cl
where the structure consists of alternating carbon atoms, with chlorine atoms attached, representing the polymer's repeating unit.
Step 8
Describe a mechanism, that involves ions, for conversion 6.
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In conversion 6, the mechanism involves the following steps:
Initiation: Chlorine (Cl2) undergoes heterolytic fission to form two chloride ions (Cl−).
Formation of Carbocation: The carbon atom adjacent to the chlorine will form a carbocation (C+) as the double bond breaks.
Nucleophilic attack: The Cl− ion attacks the carbocation, resulting in the formation of the final product.
This mechanism illustrates the importance of ionic species in facilitating organic reactions.
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