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Define electronegativity - Leaving Cert Chemistry - Question 11 - 2015

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Define electronegativity. Why is there an increase in electronegativity value moving from gallium to germanium in the periodic table? Mendeleev predicted the prope... show full transcript

Worked Solution & Example Answer:Define electronegativity - Leaving Cert Chemistry - Question 11 - 2015

Step 1

Define electronegativity.

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Answer

Electronegativity is a relative measure of the force or number expressing the attraction that an atom has for a shared pair of electrons in a covalent bond.

Step 2

Why is there an increase in electronegativity value moving from gallium to germanium in the periodic table?

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Answer

The increase in electronegativity from gallium to germanium can be attributed to two main factors:

  1. Nuclear Charge: The nuclear charge, which is the number of protons in the nucleus, increases as we move from gallium to germanium. This results in a stronger attraction between the nucleus and the electrons, raising the electronegativity.

  2. Atomic Radius: The atomic radius decreases as we move up the periodic table. A smaller atomic radius means that the valence electrons are held closer to the nucleus, which also contributes to higher electronegativity.

Step 3

Explain the basis for Mendeleev's predictions.

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Answer

Mendeleev predicted the properties of the elements gallium and germanium based on:

  1. Arrangement of Elements: He arranged the known elements in columns and groups based on their atomic weight.

  2. Similar Properties: He recognized that elements with similar properties were found in the same group, allowing him to predict the existence and properties of undiscovered elements by looking for gaps in his table.

  3. Trends: By observing trends in the properties of known elements (like increasing atomic weight), he extrapolated information about elements that had not yet been discovered, explaining their expected behavior and properties.

Step 4

Write the molecular formula for the simplest compound formed between germanium(IV) and hydrogen.

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Answer

The molecular formula for the simplest compound formed between germanium(IV) and hydrogen is GeH₄.

Step 5

Would you expect this compound to be water soluble? Justify your answer.

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Answer

No, I would not expect GeH₄ to be water soluble. This compound is classified as a non-polar solute, similar to other compounds like methane (CH₄) and silane (SiH₄). Non-polar molecules do not interact well with polar solvents like water, which is why GeH₄ would not dissolve significantly in water.

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