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Define rate of reaction - Leaving Cert Chemistry - Question 9 - 2012

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Define rate of reaction. The loss of mass of a mixture of 50 cm³ of a 2 M solution of hydrochloric acid and excess marble chips was monitored over time and the foll... show full transcript

Worked Solution & Example Answer:Define rate of reaction - Leaving Cert Chemistry - Question 9 - 2012

Step 1

Define rate of reaction.

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Answer

The rate of reaction is defined as the change in concentration of a reactant or product per unit time. It can be expressed mathematically as:

ext{Rate} = rac{ ext{change in concentration}}{ ext{time}}

Step 2

Plot a graph to show the mass of carbon dioxide produced (loss of mass) versus time.

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Answer

  1. Label the x-axis as 'Time (s)' and the y-axis as 'Loss of mass (g)'.
  2. Scale the axes appropriately to accommodate the data.
  3. Plot the points based on the provided data:
    • (0, 0.00)
    • (20, 0.10)
    • (40, 0.18)
    • (80, 0.29)
    • (120, 0.35)
    • (160, 0.39)
    • (240, 0.41)
  4. Draw a curve that accurately represents the trend of the data starting from the origin.

Step 3

Use your graph to find the instantaneous rate of the reaction at 60 seconds in g/s carbon dioxide produced.

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Answer

To find the instantaneous rate at 60 seconds:

  1. Locate 60 seconds on the time axis.
  2. Draw a tangent to the curve at this point.
  3. Determine the slope of the tangent line to find the rate, which is the change in mass over the change in time.

Step 4

Mark clearly on your graph the curve you would expect to obtain if the reaction were repeated using 50 cm³ of a 1 M solution of hydrochloric acid.

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  1. Draw a second curve on the same graph to indicate the expected results with a 1 M solution.
  2. This curve should start at the same point but rise to half the height achieved with the 2 M solution more quickly, then level off earlier, reflecting the lower concentration of HCl used.

Step 5

Justify the shape and position of this curve relative to the graph you have plotted.

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Answer

The curve for the 1 M solution will rise less steeply at the start due to the lower concentration of HCl. Additionally, it will reach a maximum mass lower than the 2 M graph and will rise to half the height of the 2 M curve, as the reaction rate is generally affected by the concentration of the reactants. It will also level off sooner, reflecting the difference in the amount of HCl present.

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