The effect of temperature on the rate of the reaction between a sodium thiosulfate solution and a hydrochloric acid solution was investigated - Leaving Cert Chemistry - Question 3 - 2020
Question 3
The effect of temperature on the rate of the reaction between a sodium thiosulfate solution and a hydrochloric acid solution was investigated. In each run, a stopwat... show full transcript
Worked Solution & Example Answer:The effect of temperature on the rate of the reaction between a sodium thiosulfate solution and a hydrochloric acid solution was investigated - Leaving Cert Chemistry - Question 3 - 2020
Step 1
With the aid of a labelled diagram describe a method for adjusting and measuring the temperature of the reaction mixture from room temperature.
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Answer
To adjust and measure the temperature of the reaction mixture, use a water bath equipped with a thermometer. Place the flask containing the sodium thiosulfate solution in the bath, and ensure that the solution reaches the desired temperature before adding hydrochloric acid. Use a thermometer to monitor the temperature of the mixture accurately as shown in the diagram.
Step 2
What was observed in the reaction flasks during each run?
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During each run, a color change was observed in the reaction mixture as solid sulfur precipitated out, causing the solution to turn increasingly opaque.
Step 3
Describe how this observation was used to obtain the times.
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The flasks were monitored visually. A cross marked below the flask was used to judge clarity; the time was recorded when the cross became obscured by the precipitate.
Step 4
Copy the last column of the table into your answer book and fill in the missing rates correct to three decimal places.
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Run 1: 0.002
Run 2: 0.005
Run 3: 0.010
Run 4: 0.018
Run 5: 0.029
Run 6: 0.062
Run 7: 0.111
Step 5
Plot a graph of initial reaction rate (r) versus temperature (T).
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For plotting the graph, the x-axis should represent the temperature in °C, while the y-axis depicts the reaction rate (r in s⁻¹). Connect the points plotted for each run with a smooth curve to demonstrate the relationship between temperature and reaction rate.
Step 6
Use your graph to find an approximate value for x in the following statement: The rate of this reaction doubles for every x °C increase in temperature.
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Answer
Using the graph, it appears that the rate doubles approximately for every increase of about 10 °C in temperature.
Step 7
Explain this result.
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Answer
The observation that the reaction rate doubles with every increase of approximately 10 °C indicates that higher temperatures enhance particle energy and frequency of collisions, leading to more effective interactions between reactants.
Step 8
Without plotting it, where would the corresponding rate for Run 8 be situated in relation to the other plotted points?
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Run 8's corresponding rate would likely be lower than the plotted points for temperatures up to 43 °C, but higher than those below it, assuming the flask affects the reaction's visibility.
Step 9
Was the depth of liquid in the flask used in Run 8 greater or less than in the original flasks? Justify your answer.
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The depth of liquid in Run 8 would be less than in the original flasks due to the different shape of the flask; a wider flask would have a lower height with the same volume, affecting the exposure of the liquid to heat.
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