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The effect of temperature on the rate of the reaction between a sodium thiosulfate solution and a hydrochloric acid solution was investigated - Leaving Cert Chemistry - Question 3 - 2020

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The effect of temperature on the rate of the reaction between a sodium thiosulfate solution and a hydrochloric acid solution was investigated. In each run, a stopwat... show full transcript

Worked Solution & Example Answer:The effect of temperature on the rate of the reaction between a sodium thiosulfate solution and a hydrochloric acid solution was investigated - Leaving Cert Chemistry - Question 3 - 2020

Step 1

With the aid of a labelled diagram describe a method for adjusting and measuring the temperature of the reaction mixture from room temperature.

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Answer

To adjust and measure the temperature of the reaction mixture, use a water bath equipped with a thermometer. Place the flask containing the sodium thiosulfate solution in the bath, and ensure that the solution reaches the desired temperature before adding hydrochloric acid. Use a thermometer to monitor the temperature of the mixture accurately as shown in the diagram.

Step 2

What was observed in the reaction flasks during each run?

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Answer

During each run, a color change was observed in the reaction mixture as solid sulfur precipitated out, causing the solution to turn increasingly opaque.

Step 3

Describe how this observation was used to obtain the times.

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Answer

The flasks were monitored visually. A cross marked below the flask was used to judge clarity; the time was recorded when the cross became obscured by the precipitate.

Step 4

Copy the last column of the table into your answer book and fill in the missing rates correct to three decimal places.

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Answer

Run 1: 0.002 Run 2: 0.005 Run 3: 0.010 Run 4: 0.018 Run 5: 0.029 Run 6: 0.062 Run 7: 0.111

Step 5

Plot a graph of initial reaction rate (r) versus temperature (T).

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Answer

For plotting the graph, the x-axis should represent the temperature in °C, while the y-axis depicts the reaction rate (r in s⁻¹). Connect the points plotted for each run with a smooth curve to demonstrate the relationship between temperature and reaction rate.

Step 6

Use your graph to find an approximate value for x in the following statement: The rate of this reaction doubles for every x °C increase in temperature.

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Answer

Using the graph, it appears that the rate doubles approximately for every increase of about 10 °C in temperature.

Step 7

Explain this result.

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Answer

The observation that the reaction rate doubles with every increase of approximately 10 °C indicates that higher temperatures enhance particle energy and frequency of collisions, leading to more effective interactions between reactants.

Step 8

Without plotting it, where would the corresponding rate for Run 8 be situated in relation to the other plotted points?

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Answer

Run 8's corresponding rate would likely be lower than the plotted points for temperatures up to 43 °C, but higher than those below it, assuming the flask affects the reaction's visibility.

Step 9

Was the depth of liquid in the flask used in Run 8 greater or less than in the original flasks? Justify your answer.

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Answer

The depth of liquid in Run 8 would be less than in the original flasks due to the different shape of the flask; a wider flask would have a lower height with the same volume, affecting the exposure of the liquid to heat.

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