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Study the reaction scheme below in which compound Y is produced by the reaction of compound X with water - Leaving Cert Chemistry - Question 8 - 2021

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Study the reaction scheme below in which compound Y is produced by the reaction of compound X with water. Y is often called isopropyl alcohol and it is a component i... show full transcript

Worked Solution & Example Answer:Study the reaction scheme below in which compound Y is produced by the reaction of compound X with water - Leaving Cert Chemistry - Question 8 - 2021

Step 1

Express its concentration in terms of moles per litre of isopropyl alcohol.

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Answer

To express the concentration of isopropyl alcohol in moles per litre, follow these steps:

  1. Determine the volume of isopropyl alcohol in the solution: Since it’s a 70% (v/v) solution, this means there are 70 cm³ of isopropyl alcohol per 100 cm³ of solution.

  2. Scale it to one litre:
    [ 70 \text{ cm}^3 \text{ of isopropyl alcohol per } 100 \text{ cm}^3 \text{ of solution} ] leads to 700 cm³ of isopropyl alcohol in one litre (1000 cm³).

  3. Convert the volume to mass using density:
    The density of isopropyl alcohol is given as 0.8 g cm³. Thus, [ 700 \text{ cm}^3 \times 0.8 \text{ g cm}^{-3} = 560 \text{ g of isopropyl alcohol} ]

  4. Calculate moles of isopropyl alcohol: The molar mass (M) of isopropyl alcohol (C₃H₈O) can be calculated as follows:

    • C: 3 × 12.01 g/mol = 36.03 g/mol
    • H: 8 × 1.008 g/mol = 8.064 g/mol
    • O: 1 × 16.00 g/mol = 16.00 g/mol

    Therefore, [ M = 36.03 + 8.064 + 16.00 = 60.094 \text{ g/mol} ]

  5. Calculate moles in one litre:
    [ \text{Moles of isopropyl alcohol} = \frac{560 \text{ g}}{60.094 \text{ g/mol}} \approx 9.3 \text{ moles} \text{ per litre} ]

Thus, the concentration of isopropyl alcohol in the hand sanitizer is approximately 9.3 moles per litre.

Step 2

What is the most influential type of intermolecular force that occurs in Z?

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Answer

The most influential type of intermolecular force in compound Z is likely to be hydrogen bonding. This can be attributed to the presence of hydroxyl groups (-OH) in alcohols, which can form strong interactions between the hydrogen of one molecule and the oxygen of another molecule. This force significantly affects the physical properties of the compound, such as its boiling point and solubility.

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