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Explain the term allotropy with reference to carbon steel.
Step 1
Answer
Allotropy refers to the ability of a material to exist in different forms. Specifically in the context of carbon steel, it pertains to how iron can adopt various crystal structures depending on the temperature and composition of the alloy. This transformation is crucial as it alters the material properties, including hardness and strength.
Step 2
Answer
The allotropy of iron is primarily observed in its two main forms: alpha iron (ferrite) and gamma iron (austenite). Alpha iron has a body-centered cubic (bcc) crystal structure, while gamma iron features a face-centered cubic (fcc) structure. The ability of carbon to dissolve within these different structures is significant in modifying the properties of steel.
Step 3
Answer
In carbon steels, up to 1.7% carbon can be accommodated in gamma iron. Upon cooling from the austenite state to ferrite, some carbon must be expelled from solution, leading to the formation of a compound known as cementite (iron carbide). This interaction between carbon and iron greatly contributes to the hardness of carbon steel.
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