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Sample Answer for Measurement of the specific latent heat of fusion of ice

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Measurement of the specific latent heat of fusion of ice

Apparatus

Ice, water, calorimeter, lagging, beakers, kitchen paper, digital thermometer reading to 0.1° C and electronic balance.

Experimental Setup

Procedure

  • Place some ice cubes in a beaker of water and keep taking the temperature with the thermometer until the ice-water mixture reaches 0° C.

  • Find the mass of the calorimeter mcalm_{cal}.

  • Half fill the calorimeter with water warmed to approximately 10° C above room temperature. Find the combined mass of the calorimeter and water m1m_1. The mass of the water is m1mcalm_1 - m_{cal}.

  • Record the initial temperature θiθ_i of the calorimeter plus water.

  • Surround the ice cubes with kitchen paper or a cloth and crush them between wooden blocks – dry them with the kitchen paper.

  • Add the pieces of dry crushed ice, a little at a time, to the calorimeter. Do this until the temperature of the water has fallen by about 20° C.

  • Record the lowest temperature θfθ_f of the calorimeter plus water plus melted ice. The rise in temperature of the ice IΔθiI Δθ_i is θf0°θ_f - 0° C and the fall in temperature of the calorimeter plus water ΔθcΔθ_c is θiθfθ_i - θ_f.

  • Find the mass of the calorimeter plus water plus melted ice m3. The mass of the melted ice mim_i is m1m2m_1 - m_2.

Detailed Setup


Measurement of the specific latent heat of fusion of ice

Physics Experiments

Results

MeasurementSymbolValue
Mass of the calorimetermcalm_{cal}=
Mass of the calorimeter plus the waterm2m_2=
Mass of the watermwm_w= m2mcalm_2 - m_{cal} =
Initial temperature of the calorimeter plus waterθ1θ_1=
Final temperature of the calorimeter plus water plus melted iceθ2θ_2=
Rise in temperature of the iceΔθiΔθ_i= θ20°Cθ_2 - 0°C =
Fall in temperature of the calorimeter plus waterΔθcΔθ_c= θ1θ2θ_1 - θ_2 =
Mass of the calorimeter plus water plus melted ice m3 = Mass of the melted icem3m_3=
mim_i= m3m2m_3 - m_2

Calculations

Assume heat losses cancel heat gains. Given that the specific heat capacity of water cw and the specific heat capacity of copper cc are already known, the latent heat of fusion of ice l may be calculated from the following equation:

Energy gained by ice = energy lost by calorimeter + energy lost by the water.

mil+micwΔθi=mcalccΔθc+mwcwΔθcm_i l + m_i c_w Δθ_i = m_{cal} c_c Δθ_c + m_w c_w Δθ_c

infoNote

If a polystyrene container is used in place of the copper calorimeter, the energy gained by the ice is equal to the energy lost by the water. The energy equation now reads:

mil+micwΔθi=mwcwΔθcm_i l + m_i c_w Δθ_i = m_w c_w Δθ_c

To avoid melting the crushed ice, transfer it with a plastic spatula.

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