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Sample Answer for Measurement of specific heat capacity of water by an electrical method

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Measurement of specific heat capacity of water by an electrical method

Apparatus

Joulemeter, calorimeter, heating coil, beaker, lagging, thermometer reading to 0.1° C, electronic balance and a low voltage a.c. supply.

Experimental Setup

Procedure

  • Find the mass of the calorimeter mcalm_{cal}.

  • Find the mass of the calorimeter plus the water m1m1. Hence the mass of the water mwm_w is m1mcalm1 - m_{cal}.

  • Set up the apparatus as shown Record the initial temperature θ1θ_1.

  • Plug in the joulemeter, switch it on and zero it.

  • Switch on the power supply and allow current to flow until a temperature rise of 10° C has been achieved.

  • Switch off the power supply, stir the water well and record the highest temperature θ2θ_2. Hence the rise in temperature ΔθΔθ is θ2θ1θ_2 - θ_1.

  • Record the final joulemeter reading Q.


Measurement of specific heat capacity of water by an electrical method

Results

Mass of the calorimeter: mcalm_{cal} =

Mass of the calorimeter plus the water: m1m_1 =

Mass of the water: mwm_w = m1mcalm_1 - m_{cal} =

Initial temperature of water: θ1θ_1 =

Final temperature: θ2θ_2 =

Rise in temperature: ΔθΔθ = θ2θ1θ_2 - θ_1 =

Final joulemeter reading: QQ =

Calculations

Given that the specific heat capacity of the calorimeter ccal is known, the specific heat capacity of water cw can be calculated from the following equation:

Electrical energy supplied = energy gained by water + energy gained by calorimeter

Q=mwcwΔθ+mcalccalΔθQ = m_w c_w Δθ + m_{cal} c_{cal} Δθ

infoNote

Given that the specific heat capacity of the calorimeter ccal is known, the specific heat capacity of water cw can be calculated from the following equation:

The energy equation now reads: Q=mwcwΔθQ = m_w c_w Δθ

If a joulemeter is unavailable, electrical energy can be supplied to the heating coil from a power supply unit connected in series to an ammeter and rheostat. A voltmeter must be placed in parallel with the heating coil to measure the potential difference and a stopwatch used to measure the time of current flow.

If a calorimeter is used the energy equation is: VIt=mwcwΔθ+mcalccalΔθVIt = m_w c_w Δθ + m_{cal} c_{cal} Δθ

If a polystyrene container is used the energy equation is: Q=mwcwΔθQ = m_w c_w Δθ

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