Electrolysis of Aqueous Solutions (OCR GCSE Chemistry A, Combined (Gateway Science Suite)): Flashcards

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Electrolysis of Aqueous Solutions
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Why is aqueous electrolysis complex?

Water produces H+H^+ & OH−OH^- ions that can react at electrodes

Ions from water dissociation

H+H^+ and OH−OH^-

Which ion reduced at cathode?

Less reactive ion

Ion oxidised at anode rule

Ion oxidised more easily

Ions at cathode in CuSO4CuSO_4 soln

Cu2+Cu^{2+} and H+H^+

Ion reduced at cathode in CuSO4CuSO_4

Cu2+Cu^{2+} (Cu less reactive than H)

Cathode equation for Cu2+Cu^{2+}

Cu2++2e−→CuCu^{2+} + 2e^- \rightarrow Cu

Product at cathode in CuSO4CuSO_4

Solid copper deposits

When is OH−OH^- oxidised at anode?

When no halide ions present

Anode equation for OH−OH^-

4OH−→2H2O+O2+4e−4OH^- \rightarrow 2H_2O + O_2 + 4e^-

Gas at anode (no halides)

Oxygen

Reactive cations like Na+Na^+ at cathode

H+H^+ reduced instead

What oxidised at anode if halides present?

Halide ions like Cl−Cl^-

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