Required Practical: Electrolysis of Aqueous Solutions (OCR GCSE Chemistry A (Gateway Science Suite)): Flashcards

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Required Practical: Electrolysis of Aqueous Solutions
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Why is aqueous electrolysis more complex?

Water produces H+H^+ and OH−OH^- ions that react at electrodes

Ions produced when water dissociates

H+H^+ and OH−OH^-

Which ion reduced at cathode in aqueous solution?

Less reactive ion

CuSO₄ electrolysis: which ion reduced at cathode?

Cu2+Cu^{2+} (copper less reactive than hydrogen)

Product at cathode in CuSO₄ electrolysis

Solid copper

Cathode equation: CuSO₄ electrolysis

Cu2+(aq)+2e−→Cu(s)Cu^{2+}(aq) + 2e^- \rightarrow Cu(s)

Product at anode in CuSO₄ electrolysis

Oxygen gas (and water)

NaCl electrolysis: which ion reduced at cathode?

H+H^+ (sodium more reactive than hydrogen)

Product at cathode in NaCl electrolysis

Hydrogen gas

Cathode equation: NaCl electrolysis

2H+(aq)+2e−→H2(g)2H^+(aq) + 2e^- \rightarrow H_2(g)

Product at anode in NaCl electrolysis

Chlorine gas

Anode equation: NaCl electrolysis

2Cl−(aq)→Cl2(g)+2e−2Cl^-(aq) \rightarrow Cl_2(g) + 2e^-

When are halide ions oxidised at anode?

When present (preferentially over OH−OH^-)

When is OH−OH^- oxidised at anode?

If no halide ions present (produces oxygen gas)

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